19099-93-5

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19099-93-5 Structure

Identification	More
[Name] 1-Cbz-4-Piperidone
[CAS] 19099-93-5
[Synonyms] 1-(BENZYLOXYCARBONYL)-4-PIPERIDINONE 1-CARBOBENZOXY-4-PIPERIDONE 1-N-CBZ-4-PIPERIDONE 1-Z-4-PIPERIDONE 4-OXO-PIPERIDINE-1-CARBOXYLIC ACID BENZYL ESTER BENZYL 4-OXO-1-PIPERIDINECARBOXYLATE BENZYL 4-OXOPIPERAZINE-1-CARBOXYLATE N-BENZYLOXYCARBONYL-4-PIPERIDONE N-BENZYLOXYCARBONYLPIPERIDIN-4-ONE N-BENZYLOXYCARBONYLPIPERIDONE N-CBZ-4-PIPERIDONE PIPERIDIN-4-ONE, CBZ PROTECTED BENZYL 4-OXO-1-PIPERIDINECARBOXYLATE, 99 % Benzyl 4-oxo-1-piperazinecarboxylate N-Benzyloxycarbonyl-4-Pipridone N-Benzyloxycarbonyl-4-piperidone, 98+% BENZYL 4-OXOPIPERIDINE-1-CARBOXYLATE 1-CBZ-4-PIPERIDONE N-Benzyloxycarbonyl-4-piperido Cbz-4-piperidone
[EINECS(EC#)] 606-227-7
[Molecular Formula] C13H15NO3
[MDL Number] MFCD00673144
[Molecular Weight] 233.26
[MOL File] 19099-93-5.mol

Chemical Properties	Back Directory
[Appearance] Colourless Oil
[Melting point ] 38-41°C
[Boiling point ] 114-140 °C/0.25 mmHg (lit.)
[density ] 1.172 g/mL at 25 °C(lit.)
[refractive index ] n20/D 1.542(lit.)
[Fp ] >110 °C
[storage temp. ] Sealed in dry,2-8°C
[solubility ] Chloroform, Dichloromethane, Ethyl Acetate, Methanol
[form ] Solid or Lliquid
[pka] -1.63±0.20(Predicted)
[color ] White to pale yellow or clear
[Specific Gravity] 1.185
[BRN ] 1533716
[InChI] InChI=1S/C13H15NO3/c15-12-6-8-14(9-7-12)13(16)17-10-11-4-2-1-3-5-11/h1-5H,6-10H2
[InChIKey] VZOVOHRDLOYBJX-UHFFFAOYSA-N
[SMILES] N1(C(OCC2=CC=CC=C2)=O)CCC(=O)CC1
[CAS DataBase Reference] 19099-93-5(CAS DataBase Reference)

Safety Data	Back Directory
[Hazard Codes ] Xi
[Risk Statements ] R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ] S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S24/25:Avoid contact with skin and eyes . S36:Wear suitable protective clothing . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ] 3
[HS Code ] 29333990

Hazard Information	Back Directory
[Chemical Properties] Colourless Oil
[Uses] Protected piperidinone that can undergo interesting synthetic transformations including the Knoevenagel reaction,1 hetero-Diels-Alder reactions,2 and reactions to form N-(4-piperidinyl)oxindoles.3
[General Description] 1-Z-4-Piperidone is the starting material in biheteroaromatic diphosphine oxides-catalyzed stereoselective direct aldol condensation reactions.

Spectrum Detail	Back Directory
[Spectrum Detail] 1-(Benzyloxycarbonyl)-4-piperidinone(19099-93-5)¹HNMR 1-(Benzyloxycarbonyl)-4-piperidinone(19099-93-5)IR

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