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ChemicalBook--->CAS DataBase List--->1155-62-0

1155-62-0

1155-62-0 Structure

1155-62-0 Structure
IdentificationMore
[Name]

N-Cbz-L-glutamic acid
[CAS]

1155-62-0
[Synonyms]

BENZYLOXYCARBONYL-L-GLUTAMIC ACID
CARBOBENZOXY-L-GLUTAMIC ACID
CBZ-GLU-OH
CBZ-L-GLUTAMIC ACID
L-GLUTAMIC ACID, N-[(PHENYLMETHOXY)CARBONYL]-
NA-CBZ-L-GLUTAMIC ACID
N-ALPHA-BENZYLOXYCARBONYL-L-GLUTAMIC-ACID
N-ALPHA-CARBOBENZOXY-L-GLUTAMIC ACID
N-ALPHA-CBZ-L-GLUTAMIC ACID
N-BENZYLOXYCARBONYL-L-GLUTAMIC ACID
N-CARBOBENZOXY-L-GLUTAMIC ACID
N-(CARBOBENZYLOXY)-L-GLUTAMIC ACID
N-CBZ-L-GLUTAMIC ACID
N-CBZ-L-GLUTAMIC ACID-OH
(S)-2-BENZYLOXYCARBONYLAMINO-PENTANEDIOIC ACID
Z-GLU-OH
Z-GLUTAMIC ACID
Z-L-GLU-OH
Z-L-GLUTAMIC ACID
n-[(phenylmethoxy)carbonyl]-l-glutamicaci
[EINECS(EC#)]

214-584-1
[Molecular Formula]

C13H15NO6
[MDL Number]

MFCD00002801
[Molecular Weight]

281.26
[MOL File]

1155-62-0.mol
Chemical PropertiesBack Directory
[Appearance]

Off-White Solid
[Melting point ]

115-117 °C(lit.)
[alpha ]

-7.4 º (c=10, CH3COOH 22 ºC)
[Boiling point ]

423.93°C (rough estimate)
[density ]

1.2801 (rough estimate)
[refractive index ]

-7.5 ° (C=8, AcOH)
[storage temp. ]

−20°C
[solubility ]

DMF, Methanol
[form ]

Solid
[pka]

3.81±0.10(Predicted)
[color ]

Off-White
[optical activity]

[α]22/D 7.4°, c = 10 in acetic acid
[BRN ]

2061272
[CAS DataBase Reference]

1155-62-0(CAS DataBase Reference)
[EPA Substance Registry System]

1155-62-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

IRRITANT
[HS Code ]

29242990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

N-benzyloxycarbonyl-L-glutamic anhydride-->Z-PYR-OH
[Preparation Products]

isoglutamine-->N-Cbz-L-Glutamic acid 5-tert-butyl ester-->L-GLUTAMIC ACID DI-TERT-BUTYLESTER DIBEN ZENESULFIMIDE SALT-->H-Glu(OMe)-OtBu-->Carbamic acid, (2,6-dioxo-3-piperidinyl)-, phenylmethyl ester (9CI)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N-Benzyloxycarbonyl-L-glutamic acid(1155-62-0).msds
Hazard InformationBack Directory
[Chemical Properties]

Off-White Solid
[Uses]

N-Cbz-L-glutamic acid is used for the synthesis.
[reaction suitability]

reaction type: solution phase peptide synthesis
Spectrum DetailBack Directory
[Spectrum Detail]

N-Cbz-L-glutamic acid(1155-62-0)MS
N-Cbz-L-glutamic acid(1155-62-0)1HNMR
N-Cbz-L-glutamic acid(1155-62-0)13CNMR
N-Cbz-L-glutamic acid(1155-62-0)IR1
N-Cbz-L-glutamic acid(1155-62-0)IR2
N-Cbz-L-glutamic acid(1155-62-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Benzyloxycarbonyl-L-glutamic acid, 99%(1155-62-0)
[Alfa Aesar]

N-Benzyloxycarbonyl-L-glutamic acid, 99%(1155-62-0)
[Sigma Aldrich]

1155-62-0(sigmaaldrich)
[TCI AMERICA]

N-Carbobenzoxy-L-glutamic Acid,>98.0%(T)(1155-62-0)
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