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ChemicalBook >> CAS DataBase List >> Hafnium(IV) chloride

Hafnium(IV) chloride

Hafnium(IV) chloride price.
  • $21.9 - $1589
  • Product name: Hafnium(IV) chloride
  • CAS: 13499-05-3
  • MF: Cl4Hf
  • MW: 320.3
  • EINECS:236-826-5
  • MDL Number:MFCD00011034
  • Synonyms:Hafnium Chloride 98+%;HafniuM(IV) chloride, -80 Mesh, 99% 25GR;HafniuM(IV) chloride 98%;HafniuM(IV) chloride purified by subliMation, 99.9% trace Metals basis;Hafnium(IV) chloride, 99.9% trace metals basis excluding Zr;Hafnium(IV) chloride, 98% trace metals basis excluding Zr;HAFNIUM(IV) CHLORIDE;(beta-4)-hafniumchloride(hfcl4
17 prices
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  • Chem-Impex
  • ProChem
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  • Strem Chemicals
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  • ManufacturerChem-Impex
  • Product number35560
  • Product descriptionHafnium(IV)chloride,98%MetalsbasisexcludingZr(Zr:≤2.7%) 98%MetalsbasisexcludingZr(Zr:≤2.7%)
  • Packaging5G
  • Price$22.4
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number35560
  • Product descriptionHafnium(IV)chloride,98%MetalsbasisexcludingZr(Zr:≤2.7%) 98%MetalsbasisexcludingZr(Zr:≤2.7%)
  • Packaging25G
  • Price$50.4
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number35560
  • Product descriptionHafnium(IV)chloride,98%MetalsbasisexcludingZr(Zr:≤2.7%) 98%MetalsbasisexcludingZr(Zr:≤2.7%)
  • Packaging100G
  • Price$173.6
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number35560
  • Product descriptionHafnium(IV) chloride ≥98% Metals basis excluding Zr (Zr : ≤ 2.7%)
  • Packaging250G
  • Price$345
  • Updated2021-12-16
  • Buy
  • ManufacturerProChem
  • Product number1954
  • Product descriptionHafnium (IV) Chloride 98+%
  • Packaging25gm
  • Price$25
  • Updated2021-12-16
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  • ManufacturerProChem
  • Product number1954
  • Product descriptionHafnium (IV) Chloride 98+%
  • Packaging100gm
  • Price$80
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number258202
  • Product descriptionHafnium(IV) chloride 98%
  • Packaging10g
  • Price$39.42
  • Updated2025-07-31
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  • ManufacturerSigma-Aldrich
  • Product number258202
  • Product descriptionHafnium(IV) chloride 98%
  • Packaging50g
  • Price$124
  • Updated2025-07-31
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  • ManufacturerSigma-Aldrich
  • Product number590592
  • Product descriptionHafnium(IV) chloride purified by sublimation, 99.9% trace metals basis
  • Packaging5g
  • Price$227
  • Updated2025-07-31
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  • ManufacturerSigma-Aldrich
  • Product number590592
  • Product descriptionHafnium(IV) chloride purified by sublimation, 99.9% trace metals basis
  • Packaging25g
  • Price$779.95
  • Updated2025-07-31
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  • ManufacturerStrem Chemicals
  • Product number72-0752
  • Product descriptionHafnium(IV) chloride, sublimed grade (99.9+%-Hf, <0.05% Zr)
  • Packaging1g
  • Price$40
  • Updated2024-03-01
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  • ManufacturerStrem Chemicals
  • Product number72-0751
  • Product descriptionHafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr)
  • Packaging10g
  • Price$70
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number72-0752
  • Product descriptionHafnium(IV) chloride, sublimed grade (99.9+%-Hf, <0.05% Zr)
  • Packaging5g
  • Price$124
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number72-0751
  • Product descriptionHafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr)
  • Packaging50g
  • Price$165
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number72-0752
  • Product descriptionHafnium(IV) chloride, sublimed grade (99.9+%-Hf, <0.05% Zr)
  • Packaging25g
  • Price$396
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number72-0751
  • Product descriptionHafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr)
  • Packaging250g
  • Price$658
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Chem-Impex 35560 Hafnium(IV)chloride,98%MetalsbasisexcludingZr(Zr:≤2.7%) 98%MetalsbasisexcludingZr(Zr:≤2.7%) 5G $22.4 2021-12-16 Buy
Chem-Impex 35560 Hafnium(IV)chloride,98%MetalsbasisexcludingZr(Zr:≤2.7%) 98%MetalsbasisexcludingZr(Zr:≤2.7%) 25G $50.4 2021-12-16 Buy
Chem-Impex 35560 Hafnium(IV)chloride,98%MetalsbasisexcludingZr(Zr:≤2.7%) 98%MetalsbasisexcludingZr(Zr:≤2.7%) 100G $173.6 2021-12-16 Buy
Chem-Impex 35560 Hafnium(IV) chloride ≥98% Metals basis excluding Zr (Zr : ≤ 2.7%) 250G $345 2021-12-16 Buy
ProChem 1954 Hafnium (IV) Chloride 98+% 25gm $25 2021-12-16 Buy
ProChem 1954 Hafnium (IV) Chloride 98+% 100gm $80 2021-12-16 Buy
Sigma-Aldrich 258202 Hafnium(IV) chloride 98% 10g $39.42 2025-07-31 Buy
Sigma-Aldrich 258202 Hafnium(IV) chloride 98% 50g $124 2025-07-31 Buy
Sigma-Aldrich 590592 Hafnium(IV) chloride purified by sublimation, 99.9% trace metals basis 5g $227 2025-07-31 Buy
Sigma-Aldrich 590592 Hafnium(IV) chloride purified by sublimation, 99.9% trace metals basis 25g $779.95 2025-07-31 Buy
Strem Chemicals 72-0752 Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <0.05% Zr) 1g $40 2024-03-01 Buy
Strem Chemicals 72-0751 Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr) 10g $70 2024-03-01 Buy
Strem Chemicals 72-0752 Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <0.05% Zr) 5g $124 2024-03-01 Buy
Strem Chemicals 72-0751 Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr) 50g $165 2024-03-01 Buy
Strem Chemicals 72-0752 Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <0.05% Zr) 25g $396 2024-03-01 Buy
Strem Chemicals 72-0751 Hafnium(IV) chloride, sublimed grade (99.9+%-Hf, <1.0% Zr) 250g $658 2024-03-01 Buy

Properties

Melting point :432 °C (lit.)
Boiling point :315.47°C (estimate)
Density :1.89 g/cm3
vapor pressure :1 mm Hg ( 190 °C)
storage temp. :Inert atmosphere,Room Temperature
solubility :Soluble in methanol and acetone.
form :Powder
color :White
Water Solubility :Soluble in water, methanol and acetone.
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Merck :14,4588
crystal system :Monoclinic
Space group :P2/c
Lattice constant :
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.63270.73770.6290109.05900.2735

Exposure limits :ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3 InChIKey :PDPJQWYGJJBYLF-UHFFFAOYSA-J
CAS DataBase Reference :13499-05-3(CAS DataBase Reference)
EPA Substance Registry System :Hafnium chloride (HfCl4), (T-4)- (13499-05-3)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning GHS hazard pictograms P234, P390, P404
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Hafnium(IV) chloride is used as a precursor for catalyst involved in the Ziegler-Natta polymerization of propylene. It is an effective Lewis acid for various applications in organic synthesis viz alkylation of ferrocene. Further, it increases the rate and control of 1,3-dipolar cycloadditions. It is also used to prepare hafnium dioxide and hafnium silicate, which is used as high-k-dielectrics in the production of integrated circuits.

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