二苯基硅烷(775-12-2)質(zhì)譜(MS)

產(chǎn)品名稱:二苯基硅烷

CAS:775-12-2

分子式:C12H12Si

分子量: 184.31

InChI:InChI=1S/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2

InChIKey: VDCSGNNYCFPWFK-UHFFFAOYSA-N

Smiles:[SiH2](C1=CC=CC=C1)C1=CC=CC=C1

¹HNMR

¹³CNMR

IR1

Mass

MS-IW-8155          
diphenylsilane
C12H12Si            (Mass of molecular ion:    184)

   Source Temperature: 220 °C
   Sample Temperature: 150 °C
   Reservoir, 75 eV

      29.0       1.0
      50.0       1.1
      51.0       2.5
      53.0      10.9
      54.0       2.0
      55.0       2.1
      66.0       1.0
      67.0       1.0
      77.0       3.0
      78.0       2.5
      79.0       7.9
      80.0       2.1
      81.0       2.4
      91.0       2.8
     103.0       4.2
     104.0       1.4
     105.0      59.8
     106.0     100.0
     107.0      16.8
     108.0       4.4
     129.0       2.1
     131.0       1.3
     152.0       1.0
     153.0       1.3
     154.0       1.3
     155.0       3.9
     179.0       1.1
     180.0       4.3
     181.0      14.4
     182.0       5.4
     183.0      22.8
     184.0      62.6
     185.0      11.7
     186.0       3.0

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₁₂ H₁₂ Si	0.05 ml : 0.5 ml CDCl₃
diphenylsilane

    Assign.     Shift(ppm)

      A             7.578
      B             7.362
      C             7.329
      D             4.932

     Hz     ppm     Int.

   3036.50   7.598     52
   3035.40   7.596    112
   3033.57   7.591    534
   3031.98   7.587    608
   3030.52   7.583    293
   3028.81   7.579     99
   3027.83   7.577    234
   3026.86   7.574    257
   3025.88   7.572    641
   3024.05   7.567    634
   3021.12   7.560     54
   2954.47   7.393     51
   2952.88   7.389    101
   2951.29   7.385     68
   2949.34   7.380     77
   2945.43   7.371    327
   2942.63   7.364    130
   2940.31   7.358    289
   2938.60   7.353    452
   2936.77   7.349    254
   2936.04   7.347    188
   2934.94   7.344    470
   2934.20   7.342    545
   2932.74   7.339    347
   2928.47   7.328    342
   2927.12   7.325    576
   2926.51   7.323    457
   2922.00   7.312    116
   2920.65   7.309    227
   2919.92   7.307    154
   2918.46   7.303    185
   2070.80   5.182     35
   1971.19   4.933   1000
   1871.46   4.683     35

in CDCl3