雙環(huán)己酮草酰二腙(370-81-0)紅外圖譜(IR1)
分子式:C14H22N4O2
分子量: 278.35
InChI:InChI=1S/C14H22N4O2/c19-13(17-15-11-7-3-1-4-8-11)14(20)18-16-12-9-5-2-6-10-12/h1-10H2,(H,17,19)(H,18,20)
InChIKey: DSRJIHMZAQEUJV-UHFFFAOYSA-N
Smiles:C1(/CCCCC/1)=N/NC(=O)C(=O)N/N=C1\CCCCC\1
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Mass
MS-NW-0386
oxalic acid bis(cyclohexylidenehydrazide)
C14H22N4O2 (Mass of molecular ion: 278)
Source Temperature: 160 °C
Sample Temperature: 160 °C
Direct, 75 eV
18.0 1.3
27.0 2.7
28.0 1.4
29.0 3.1
30.0 2.5
39.0 3.7
41.0 12.3
42.0 3.9
43.0 1.1
53.0 2.5
54.0 7.9
55.0 13.3
56.0 1.2
67.0 4.9
68.0 2.6
69.0 7.0
79.0 1.2
81.0 3.3
82.0 2.1
84.0 1.6
94.0 1.0
95.0 1.3
96.0 5.3
97.0 6.2
98.0 18.7
99.0 1.3
111.0 1.9
112.0 18.8
113.0 1.7
137.0 1.0
138.0 1.1
139.0 100.0
140.0 9.1
235.0 1.5
278.0 5.9
279.0 1.0
400 MHz in CDCl3
90 MHz in CDCl3
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| 1H NMR |
399.65 MHz |
| C14 H22 N4 O2
|
0.039 g : 0.5 ml CDCl3
|
| oxalic acid bis(cyclohexylidenehydrazide)
|
 |
Assign. Shift(ppm)
A 10.1
B *1 2.465
C *1 2.404
D 1.76
E 1.68
|
Hz ppm Int.
4029.08 10.082 599
991.67 2.482 747
985.57 2.467 1000
979.00 2.450 858
967.71 2.422 633
961.61 2.407 968
955.05 2.390 781
720.21 1.803 154
714.26 1.788 368
708.01 1.772 683
702.21 1.758 776
696.11 1.742 750
690.46 1.728 518
683.75 1.711 311
678.25 1.698 364
675.96 1.692 392
672.15 1.682 567
667.88 1.672 544
660.55 1.653 272
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| 1H NMR |
89.56 MHz |
| C14 H22 N4 O2
|
0.046 g : 0.5 ml CDCl3
|
| oxalic acid bis(cyclohexylidenehydrazide)
|
|
Assign. Shift(ppm)
A 10.06
B 2.427
C 1.87 to 1.62
|
Hz ppm Int.
900.56 10.056 163
221.06 2.469 474
215.00 2.401 593
209.50 2.340 257
209.19 2.336 257
205.81 2.299 60
169.63 1.895 58
169.13 1.889 59
168.31 1.880 64
167.50 1.871 84
164.13 1.833 171
163.75 1.829 175
160.19 1.789 314
153.75 1.717 1000
152.06 1.698 981