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2,2,6-???????????

2,2,6-???????????
2,2,6-??????????? ??? ???
?? ??:
2408-37-9
???:
2,2,6-???????????
???(??):
2,2,6-???????????
???:
2,2,6-TRIMETHYLCYCLOHEXANONE
???(??):
Cyclohexanone, 2,2,6-trimethyl-;2,6,6-Trimethylcyclohexanone;2,2,6-Trimethylcyclohexan-1-one;FEMA 3473;2,2,6-TRIMETHYLCYCLOHEXANONE;2,2,6-trimethyl-cyclohexanon;1,1,3-Trimethyl-2-cyclohexanone;2 2 6-TRIMETHYLCYCLOHEXANONE 98+%;2,2,6-TRIMETHYLCYCLOHEXANONE, 98.5+%;2,2,6-TRIMETHYLCYCLOHEXANONE 98.5+% (GC)
CBNumber:
CB9155613
???:
C9H16O
??? ??:
140.22
MOL ??:
2408-37-9.mol

2,2,6-??????????? ??

???
-31.8°C
?? ?
178-179 °C(lit.)
??
0.904 g/mL at 25 °C(lit.)
???
n20/D 1.447(lit.)
FEMA
3473 | 2,2,6-TRIMETHYLCYCLOHEXANONE
???
125 °F
?? ??
Flammables area
???
?????(?? ???), ???(?? ???)
??? ??
??
??
??
Specific Gravity
0.904
??
????? ??? ? 10.00%. ?? thujone labdanum ? cistus
?? ??
?? ?????
???
?? ?? ??.
JECFA Number
1108
BRN
1905593
LogP
2.41
CAS ??????
2408-37-9(CAS DataBase Reference)
EPA
2,2,6-Trimethylcyclohexanone (2408-37-9)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
?? ???? ?? 10
????? 23-24/25
????(UN No.) UN 1224 3/PG 3
WGK ?? 3
TSCA Yes
?? ?? 3
???? III
???? ?? KE-34453
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?:
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P210 ?·???·??·????? ????? - ?? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
2
0 0

2,2,6-??????????? C??? ??, ??, ??

??? ??

CLEAR COLOURLESS LIQUID

??

Reported found in bilberries, passion fruit and tea. Also reported found in apricot, bilberry, white wine, black tea, green tea, microbial fermented tea, brewed tea, yellow passion fruit juice and dill herb.

??

2,2,6-Trimethylcyclohexanone is used as a flavoring agent. It is also used to prepare terpene viz. beta-ionone.

Purification Methods

Purify it via the semicarbazone (m 218o, from MeOH or EtOH), decompose this in the usual way (cf p 65 and 67, or MEK, p 106) and fractionally distil the liquid ketone through a vigreux column (p 11) at ~760mm. [Chakravarti J Chem Soc 1567 1947, Milas et al. J Am Chem Soc 70 1831 1948, Beilstein 7 I 24, 7 II 32, 7 III 7.]

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