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2090-05-3
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???(??):
?????;?????(CALCIUMBENZOATE);???????
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Calcium benzoate
???(??):
CALCIUM BENZOATE;Calciumdibenzoat;calcium dibenzoate;Benzoic acid calcium;Benzoicacid,calciumsalt;CALCIUM BENZOATE REAGENT;Dibenzoic acid calcium salt;Di(benzoic acid)calcium salt;Bis(benzoic acid)calcium salt;Benzoic acid, calcium salt (2:1)
CBNumber:
CB8348713
???:
C7H8CaO2
??? ??:
164.22
MOL ??:
2090-05-3.mol
MSDS ??:
SDS

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?? ?
249.2℃[at 101 325 Pa]
??
1.42[at 20℃]
???
0.093Pa at 25℃
???
?? ?????(0°C?? 2.6g/100ml).
LogP
1.87
CAS ??????
2090-05-3(CAS DataBase Reference)
EPA
Calcium benzoate (2090-05-3)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
TSCA Yes
???? ?? KE-02703
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
1
0 0

?? ??? C??? ??, ??, ??

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? (1) ?? : ? ?? 2% ???? ?????? ???? ?? ???? ???? ?? ??? ? 105℃?? 4?? ???? ??? ??? ? 121.5~123.5℃??? ??.

??(2) ???? : ? ?? 10g? ?? 100mL? ??? ???? ?? ??? ?? ?? ???? ?????(1G4)? ??? ?? ???? ?? ?????? ?? 105℃?? 2?? ??? ? ??????? ??? ??? ?, ? ?? 0.3% ????? ??.

??(3) ??? ? ????? : ? ?? 2g? ??? ?? ?? 20mL? ??? ???????? 2~3??? ?? ?? 0.1N ???????? ?? 0.1N ???? ??? ?, 0.5mL ?? ????? ?? ??.

??(4) ????? : ? ?? 0.25g? ? 10mL? ??? ??? ??? ? ??? ?? ? ???? ???? ???? 0.5g? ?? ??? ?? ? 10?? ? 600℃? ????. ?? ?? ???? ???? 20mL? ?? ???? 0.1N ????? 0.5mL? ??? ?? ?????? ??. ??, 0.1N ????? 0.5mL ? 0.01N ?? 0.5mL? ?? ??? ????? ??? ??? ??? ?, ????? ???? ??? ???? ???? ?? ????? ??.

??(5) ???? : ? ?? 1g? ??? ?? 「?????」? ???? (8)? ?? ????(10ppm ??).

??(6) ?? : ? ??? ?????? ?? ??? ?, ? ?? 4.0ppm ????? ??.

??(7) ? : ? ?? 5.0g? ??? ??????? ?? ?????????????? ?? ??? ?, ? ?? 2.0ppm ????? ??.

??(8) ?? : ? ??? ?????? ?? ??? ?, ? ?? 1.0ppm ????? ??.

??(9) ???? ?? ?? : ? 100mL? ?? 1.5mL? ??? ???? 0.1N ????????? ??? 30?? ??? ??? ???? ??? ? ? ?? ? ?? 1g? ??? ? 70℃?? 0.1N ?????????? ??? 15?? ??? ??? ??? ?, ? ?? 0.5mL ????? ??.

????

? ? ??? ????? ? ????? ? ???? ??? ????.

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? ? ??? ??? ?? 0.6g? ??? ?? ? 20mL ? ???? 2mL? ??? ?? ???? 100mL? ??. ? ?? 0.05M ?.?.?.???? ? 30mL? ? ??? ???? ??? ???????? 15mL ? ???????? 0.25g? ?? ?? 0.05M ?.?.?.?????? ????.

0.05M ?.?.?.???? 1mL =14.116mg C14H10CaO4

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Calcium benzoate refers to the calcium salt of benzoic acid. When used in the food industry as a preservative, its E number is E213 (INS number 213); it is approved for use as a food additive in the EU, USA and Australia and New Zealand.
The formulas and structures of calcium carboxylate derivatives of calcium and related metals are complex. Generally the coordination number is eight and the carboxylates form Ca-O bonds. Another variable is the degree of hydration.

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White or colorless orthorhombic crystals or a white powder. It has slight solubility in water and high solubility in hot water. The compound is highly stable at room temperature.

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Calcium benzoate hydrate is used in used in the food industry as a preservative. It is also utilized as a preservative and growth promoter in the feed industry.

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Calcium benzoate is prepared by reacting benzoic acid and calcium bicarbonate.

Purification Methods

Calcium benzoate (3H2O) [2090-05-3] M 336.4. Recrystallise it from water (10m/g) between 90o and 0o. [Beilstein 9 I 60, 9 H 85, 9 III 377, 9 IV 280.]

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