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D-GALACTONO-1,4-LACTONE

D-GALACTONO-1,4-LACTONE ??? ???
?? ??:
2782-07-2
???:
D-GALACTONO-1,4-LACTONE
???(??):
C03383;D-GALACTONOLACTONE;D-GALACTONO-G-LACTONE;1,4-D-Galactonolactone;D-GALACTONO-1,4-LACTONE;GAMMA-D-GALACTONOLACTONE;GALACTONO-1,4-LACTONE, D-;D-GALACTONO-GAMMA-LACTONE;Glucuronic Acid Impurity 14;D(-)-GALACTONO-GAMMA-LACTONE
CBNumber:
CB7184646
???:
C6H10O6
??? ??:
178.14
MOL ??:
2782-07-2.mol

D-GALACTONO-1,4-LACTONE ??

???
137°C
?? ?
467.9±18.0 °C(Predicted)
??
1.766±0.06 g/cm3(Predicted)
???
DMSO(?? ???), ?(?? ???)
??? ??
??
??? ??
??? ??
?? ?? (pKa)
12.06±0.60(Predicted)
??
???? ?????
LogP
-3.400 (est)
CAS ??????
2782-07-2(CAS DataBase Reference)
EPA
D-Galactonic acid, .gamma.-lactone (2782-07-2)

??

????? 22-24/25
HS ?? 29322090
???? ?? KE-17408

D-GALACTONO-1,4-LACTONE C??? ??, ??, ??

??

D-Galactono-1,4-lactone was used in carbohydrate research as an elution compound for the purification process of exo-β-D-galactofuranosidase enzyme.

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ChEBI: A galactonolactone derived from D-galactonic acid.

Purification Methods

Crystallise the lactone from EtOH, aqueous EtOH, MeOH or EtOAc. It is also purified by passage through a column of Amberlite IR-120 (H+ form), and the effluent and washings are then freeze-dried [Wolfrom & Thompson Methods in Carbohydrate Chemistry I 67 1963, Academic Press]. The 5,6-O-isopropylidene-D-galactono-1,4-lactone is purified by chromatography (EtOAc) and has m 165-167o (from EtOH/hexane), and 167.5-168.5o (from Me2CO/*C6H6) [NMR: Copel & Stick Aust J Chem 31 1371 1978.] [Beilstein 18 III/IV 3026, 18/5 V 18.]

D-GALACTONO-1,4-LACTONE ?? ?? ? ???

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D-GALACTONO-1,4-LACTONE ?? ??

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