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Diethylaminosulfur trifluoride

Diethylaminosulfur trifluoride ??? ???
?? ??:
38078-09-0
???:
Diethylaminosulfur trifluoride
???(??):
DAST;ET2NSF3;DIETHYLAMINOSULPHUR TRIFLUORIDE;(diethylamino)trifluorosulfur;Diethylamine sulfur trifluoride;amino)suL;fur trifL;(beta-4)-sulfu;(T-4)-(N-ethyl;Oleamide 301-02-0
CBNumber:
CB5153161
???:
C4H10F3NS
??? ??:
161.19
MOL ??:
38078-09-0.mol
MSDS ??:
SDS

Diethylaminosulfur trifluoride ??

?? ?
30-32 °C3 mm Hg(lit.)
??
1.22 g/mL at 25 °C(lit.)
???
1.41-1.416
???
75 °F
?? ??
2-8°C
???
??, ?????(??) ? ???
?? ?? (pKa)
-4.87±0.70(Predicted)
??? ??
??
Specific Gravity
1.220
??
??~??~???
???
??? ????
??
Moisture Sensitive
Merck
14,3113
BRN
1849066
?? ??
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
???
Reacts with Moisture in the Air, Reacts With Moisture In The Air, Unstable in So
InChIKey
CSJLBAMHHLJAAS-UHFFFAOYSA-N
CAS ??????
38078-09-0(CAS DataBase Reference)
NIST
Diethylaminosulfur trifluoride(38078-09-0)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C,T,F
?? ???? ?? 10-14-20/21/22-34-5-35-40
????? 16-26-36/37/39-45
????(UN No.) UN 2920 8/PG 1
WGK ?? 3
F ?????? 3-10-21
?? ?? ?? Corrosive/Keep Cold
?? ?? 8
???? I
HS ?? 29309070
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
H242 ???? ??? ??? ? ?? ????? ?? ? ???;?????? ?? C, D,?? E, F
?? G
??
??
GHS hazard pictograms P210, P220, P234, P280, P370+P378,P403+P235, P411, P420, P501
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P370+P378 ?? ? ?? ?? ?? (Section 5. ??, ??? ????? ??? ???)?(?) ?????.
P403+P235 ??? ? ?? ?? ???? ???? ?????.
NFPA 704
3
3 2
W

Diethylaminosulfur trifluoride MSDS


DAST

Diethylaminosulfur trifluoride C??? ??, ??, ??

??? ??

Pale yellow liquid. Soluble in most non-polar organic solvents, commonly used in CH2Cl2, CHCl3 and CCl4.

??

Diethylaminosulfur Trifluoride is a very useful Nucleophilic fluorinating agent in chemical synthesis. It is also used as a reagent in the preparation of 2-thiazolines from (1,2)-thioam ido-alcohols.

?? ??

Diethylaminosulfur trifluoride (DAST) is used as a precursor to prepare 2,6-dimethoxybenzoyl fluoride and 2-thiazolines. It is a useful fluorinating agent used for a variety of compounds including alcohols, thioethers, alkenols and cyanohydrins. It also serves as a catalyst for Friedel-Crafts allylation reaction using tertiary cyclopropyl silyl ethers and in the rearrangement of homoallylic alcohols to unsaturated aldehydes. It plays an important role for gem difluorination of ketopipecolinic acids.

Diethylaminosulfur trifluoride ?? ?? ? ???

???

?? ??


Diethylaminosulfur trifluoride ?? ??

???( 462)?? ??
??? ?? ??? ?? ?? ? ??
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Diethylaminosulfur trifluoride ?? ??:

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