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????????? ??? ???
?? ??:
606-28-0
???:
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???(??):
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Methyl 2-benzoylbenzoate
???(??):
OBM;MBB;OMBB;PI-OMBB;YF-PI OMBB;IHT-PI OMBB;HRcure-OMBB;OMNIRADOMBB;PHOTOCURE 55;Syna-PI OMBB
CBNumber:
CB2287191
???:
C15H12O3
??? ??:
240.25
MOL ??:
606-28-0.mol
MSDS ??:
SDS

????????? ??

???
48-53 °C (lit.)
?? ?
352 °C
??
1,69 g/cm3
???
0Pa at 20℃
???
1.5740 (estimate)
???
>230 °F
?? ??
Sealed in dry,Room Temperature
???
Insoluble in water
??? ??
powder to crystal
??
White to Orange to Green
???
117.7mg/L at 20℃
InChIKey
NQSMEZJWJJVYOI-UHFFFAOYSA-N
LogP
2.8 at 25℃
CAS ??????
606-28-0(CAS DataBase Reference)
NIST
Benzoic acid, 2-benzoyl-, methyl ester(606-28-0)
EPA
Methyl o-benzoylbenzoate (606-28-0)
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  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? N
?? ???? ?? 50/53
????? 60-61
????(UN No.) UN 3077 9/PG 3
WGK ?? 3
HS ?? 29183000
???? ?? KE-23503
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? GHS hazard pictograms P273, P391, P501
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P273 ???? ???? ???.
P391 ???? ????.
P501 ...? ??? / ??? ?? ???.

????????? MSDS


2-Benzoyl benzoic acid methyl ester

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White or yellowish granule crystals, soluble in alcohol and alkali solution, almost insoluble in water when precipitated in acid.

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Methyl 2-benzoylbenzoate is used as an anti-ultraviolet absorber and a preservative for food and beverages.

?? ??

Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.

?? ??

Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate. It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst. Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.

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