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??????????(???????)???(I) ??? ???
?? ??:
17250-25-8
???:
??????????(???????)???(I)
???(??):
??????????(???????)???(I)
???:
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
???(??):
Ir18.6%min;Einecs 241-282-7;Dichlorodicarbonyl ruthenium;carbonylhydrotris(triphenylphosphine)iridium;carbonylhydrotris(triphenylphosphine)-iridiu;Hydrocarbonyltris(triphenylphosphine)iridium;Iridium, carbonylhydrotris(triphenylphosphine)-;Hydridocarbonyltris-(triphenylphosphino)-iridium;hydridocarbonyltris (triphenylphosphine) iridiuM;CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CBNumber:
CB0195708
???:
C55H45IrOP3
??? ??:
1007.08
MOL ??:
17250-25-8.mol

??????????(???????)???(I) ??

???
170°C (dec.)
?? ??
under inert gas (nitrogen or Argon) at 2-8°C
???
?????? ???? ???
??? ??
??
??
???
??
Moisture Sensitive
CAS ??????
17250-25-8
EPA
Iridium, carbonylhydrotris(triphenylphosphine)- (17250-25-8)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn
?? ???? ?? 36/37/38
????? 26-36/37/39
????(UN No.) UN2813
TSCA Yes
HS ?? 2843.90.0000
?? ?? 4.3
???? III
????(GHS): GHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P304+P340 ???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
1
2 0

??????????(???????)???(I) C??? ??, ??, ??

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pale yellow powder

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Hydridocarbonyltris(triphenylphosphine)iridium (I) (CAS# 17250-25-8) is a useful reagent used for Si-C bond cleavage, and as a catalyst in the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.

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