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ChemicalBook >> CAS DataBase List >>Cyclopentadienylzirconium trichloride

Cyclopentadienylzirconium trichloride

CAS No.
34767-44-7
Chemical Name:
Cyclopentadienylzirconium trichloride
Synonyms
zirconium(IV) trichL;Cyclopentadienylzirkoniumtrichlorid;CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE;TRICHLORO(CYCLOPENTADIENYL)ZIRCONIUM(IV);CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE, 9;(Cyclopentadienyl)zircornium trichloride;CYCLOPENTADIENYLZIRCONIUM(IV) TRICHLORIDE;Cyclopentadienylzirconium trichloride, 98+%;Cyclopentadienylzirconiumtrichloride,min.98%;Cyclopentadienylzirconium(IV) Trichloride >
CBNumber:
CB9446326
Molecular Formula:
C5Cl3Zr
Molecular Weight:
257.63
MDL Number:
MFCD00015756
MOL File:
34767-44-7.mol
Last updated:2025-01-27 09:38:02

Cyclopentadienylzirconium trichloride Properties

Melting point 210 °C (dec.)(lit.)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color off-white to tan
Water Solubility reacts
Sensitive Moisture Sensitive
CAS DataBase Reference 34767-44-7(CAS DataBase Reference)
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34-29-20/21/22
Safety Statements  26-27-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  II
HS Code  29319090
NFPA 704
0
3 0
W

Cyclopentadienylzirconium trichloride price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 475203 Cyclopentadienylzirconium(IV) trichloride 97% 34767-44-7 1g $76.7 2024-03-01 Buy
TCI Chemical C1995 Cyclopentadienylzirconium(IV) Trichloride >96.0%(T) 34767-44-7 1g $55 2021-12-16 Buy
Alfa Aesar 020617 Cyclopentadienylzirconium trichloride, 98+% 34767-44-7 5g $260 2023-06-20 Buy
Alfa Aesar 020617 Cyclopentadienylzirconium trichloride, 98+% 34767-44-7 250mg $20.1 2021-12-16 Buy
Strem Chemicals 40-1100 Cyclopentadienylzirconium trichloride, min. 98% 34767-44-7 1g $62 2024-03-01 Buy
Product number Packaging Price Buy
475203 1g $76.7 Buy
C1995 1g $55 Buy
020617 5g $260 Buy
020617 250mg $20.1 Buy
40-1100 1g $62 Buy

Cyclopentadienylzirconium trichloride Chemical Properties,Uses,Production

Chemical Properties

white to light brown powder. Insoluble in most noncoordinating solvents; however, it becomes soluble in benzene or chloroform in the presence of two equiv of donor agents such as ether, THF, triethylamine, or pyridine.

Uses

Catalyst for:

  • Homo- and copolymerization reactions
  • Catalytic dehydrogenation of cyclooctane
  • Cross-coupling reaction of aryl fluorides with a phenethyl Grignard reagents

reaction suitability

core: zirconium
reagent type: catalyst

Synthesis

Trichloro(cyclopentadienyl)zirconium is prepared by the photoinduced chlorination of Dichlorobis(cyclopentadienyl)zirconium.

Cyclopentadienylzirconium trichloride Preparation Products And Raw materials

Raw materials

Preparation Products

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CYCLOPENTADIENYLZIRCONIUM(IV) TRICHLORIDE CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE TRICHLORO(CYCLOPENTADIENYL)ZIRCONIUM(IV) Cyclopentadienylzirconium trichloride, 98+% CYCLOPENTADIENYLZIRCONIUM TRICHLORIDE, 9 Cyclopentadienylzirkoniumtrichlorid Cyclopentadienyl Zirconium Trichloride (CpZrCl3) Cyclopentadienylzirconium trichloride, min. 98% CyclopentadienylzirconiuM trichloride, 98% 1GR Cyclopentadienylzirconiumtrichloride,min.98% Trichloro(η5-2,4-cyclopentadien-1-yl)zirconium (Cyclopentadienyl)zircornium trichloride Cyclopentadienylzirconium(IV) Trichloride > zirconium(IV) trichL Cyclopentadienylzirconium trichloride ISO 9001:2015 REACH 34767-44-7 C5H5ZrCl3 C5H5Cl3Zr CpZrCl3 Catalysis and Inorganic Chemistry Zirconium Homogeneous Catalysts Classes of Metal Compounds Titanium Alkoxides, etc. (Homogeneous Catalysts) Metallocenes Half Metallocenes Catalysts for Organic Synthesis Transition Metal Compounds Zr (Zirconium) Compounds Zr metallocene Zr (Zirconium) Compounds Catalysts for Organic Synthesis Classes of Metal Compounds Half Metallocenes Homogeneous Catalysts Metallocenes Synthetic Organic Chemistry Titanium Alkoxides, etc. (Homogeneous Catalysts) Transition Metal Compounds Catalysis and Inorganic Chemistry Chemical Synthesis Zirconium