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ChemicalBook--->CAS DataBase List--->99769-19-4

99769-19-4

99769-19-4 Structure

99769-19-4 Structure
IdentificationMore
[Name]

3-Methoxycarbonylphenylboronic acid
[CAS]

99769-19-4
[Synonyms]

3-(METHOXYCARBONYL)BENZENEBORONIC ACID
3-METHOXYCARBONYLPHENYLBORONIC ACID
AKOS BRN-0125
METHYL 3-BORONOBENZOATE
M-(METHOXYCARBONYL)PHENYLBORONIC ACID
3-METHOXYCARBONYLPHENYLBARONIC ACID
3-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
[Molecular Formula]

C8H9BO4
[MDL Number]

MFCD02093046
[Molecular Weight]

179.97
[MOL File]

99769-19-4.mol
Chemical PropertiesBack Directory
[Appearance]

White to light yellow crystal powde
[Melting point ]

205-208 °C(lit.)
[Boiling point ]

359.9±44.0 °C(Predicted)
[density ]

1.25±0.1 g/cm3(Predicted)
[storage temp. ]

Refrigerator (+4°C)
[form ]

Powder
[pka]

7.74±0.10(Predicted)
[color ]

White to off-white
[Water Solubility ]

Reacts with water.
[InChI]

InChI=1S/C8H9BO4/c1-13-8(10)6-3-2-4-7(5-6)9(11)12/h2-5,11-12H,1H3
[InChIKey]

ALTLCJHSJMGSLT-UHFFFAOYSA-N
[SMILES]

C(OC)(=O)C1=CC=CC(B(O)O)=C1
[CAS DataBase Reference]

99769-19-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29319099
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->Magnesium-->Triisopropyl borate-->Bis(2-dimethylaminoethyl) ether-->Methyl 3-iodobenzoate
[Preparation Products]

METHYL 3'-NITRO[1,1'-BIPHENYL]-3-CARBOXYLATE-->3-(3-Carbamoylphenyl)benzoic acid-->Methyl 3-(3-hydroxymethylphenyl)benzoate-->METHYL 3-(OXETAN-3-YL)BENZOATE-->4'-AMINO-BIPHENYL-3-CARBOXYLIC ACID METHYL ESTER-->Methyl 3-(2-carboxyphenyl)benzoate
Hazard InformationBack Directory
[Chemical Properties]

White to light yellow crystal powde
[Uses]

3-Methoxycarbonylphenylboronic acid can be used in the preparation of substituted pyrazolylpyrimidinamine derivative for use as protein kinase inhibitors and suzuki reaction.
[Uses]

Reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.
[Uses]

suzuki reaction
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Methoxycarbonylphenylboronic acid, 97%(99769-19-4)
[Alfa Aesar]

3-(Methoxycarbonyl)benzeneboronic acid, 97%(99769-19-4)
[Sigma Aldrich]

99769-19-4(sigmaaldrich)
[TCI AMERICA]

3-(Methoxycarbonyl)phenylboronic Acid  (contains varying amounts of Anhydride)(99769-19-4)
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