| Identification | More | [Name]
2-Bromobenzoic acid | [CAS]
88-65-3 | [Synonyms]
2-BROMOBENZOIC ACID
O-BROMOBENZOIC ACID
RARECHEM AL BO 0014
2-bromo-benzoicaci
Benzoic acid, o-bromo-
benzoicacid,2-bromo-
bromobenzoicacid
o-bromo-benzoicaci
2-Bromobenzoic aicd
2-Brom-benzoic acid
Brombenzoicacid,95%
2-Bromobenzene carboxylic acid
o-Bromobenzoic Acid 2-Bromobenzoic Acid
O-BROMOBENZOIC ACID CRYSTALLINE
2-BROMO BENZOIC ACID FOR SYNTHESIS
EINECS2
2-bromobenzoate
2-Brombenzoesure | [EINECS(EC#)]
201-848-6 | [Molecular Formula]
C7H5BrO2 | [MDL Number]
MFCD00002402 | [Molecular Weight]
201.02 | [MOL File]
88-65-3.mol |
| Chemical Properties | Back Directory | [Appearance]
White to light yellow crystal powder | [Melting point ]
147-150 °C (lit.) | [Boiling point ]
86 °C(Press: 4-5 Torr) | [density ]
1,929 g/cm3 | [vapor pressure ]
>1 mm Hg ( 20 °C)
| [refractive index ]
1.6080 (estimate) | [Fp ]
>100°C | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
95% ethanol: soluble100mg/mL, clear, colorless to yellow | [form ]
Powder | [pka]
2.84(at 25℃) | [color ]
White to light yellow or beige | [Water Solubility ]
slightly soluble | [Detection Methods]
GC,NMR | [BRN ]
971266 | [InChIKey]
XRXMNWGCKISMOH-UHFFFAOYSA-N | [CAS DataBase Reference]
88-65-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzoic acid, 2-bromo-(88-65-3) | [EPA Substance Registry System]
88-65-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes.
R37/38:Irritating to respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
DG4448035
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29163900 |
| Hazard Information | Back Directory | [Chemical Properties]
White to light yellow crystal powder | [Uses]
2-Bromobenzoic acid was used in the synthesis of new zinc(II) ? 2-bromobenzoate complex compounds. It was used as the starting reagent in the synthesis of hemilabile benzimidazolyl phosphine ligands. | [Synthesis Reference(s)]
Canadian Journal of Chemistry, 43, p. 1306, 1965 DOI: 10.1139/v65-178
The Journal of Organic Chemistry, 59, p. 4042, 1994 DOI: 10.1021/jo00094a007 | [General Description]
2-Bromobenzoic acid (2-BA) on condensation with aminoquinolines yields phenylquinolylamines. 2-BA is the common building block for synthesis of various nitrogen heterocycles. | [Purification Methods]
Crystallise the acid from *C6H6 or MeOH. The anilide has m 141o (from EtOH/H2O). [Beilstein 9 IV 1011.] | [Toxics Screening Level]
The ITSL for o-bromobenzoic acid has been changed from 0.04 μg/m3 to 0.1 μg/m3 based on an annual averaging time. |
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