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ChemicalBook--->CAS DataBase List--->85857-16-5

85857-16-5

85857-16-5 Structure

85857-16-5 Structure
IdentificationMore
[Name]

1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE
[CAS]

85857-16-5
[Synonyms]

1H,1H,2H,2H-PERFLUOROOCTYLTRIMETHOXYSILANE
(TRIDECAFLUORO-1,1,2,2-TETRAHYDROOCTYL)TRIMETHOXYSILANE
Perfluorooctyltrimethoxysilane
trimethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)silane
1H,1H,2H,2H-Perfluorooctyltrimethoxysilane 97%
1H,1H,2H,2H-Perfluorooctyltrimethoxysilane97%
trimethoxytridecafluorooctylsilane
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-(trimethoxysilyl)octane
2-(Tridecafluorohexyl)ethyltrimethoxysilane
[EINECS(EC#)]

288-657-1
[Molecular Formula]

C11H13F13O3Si
[MDL Number]

MFCD00153261
[Molecular Weight]

468.28
[MOL File]

85857-16-5.mol
Chemical PropertiesBack Directory
[Melting point ]

<0°C
[Boiling point ]

88 °C
[density ]

1.457
[vapor pressure ]

13Pa at 25℃
[refractive index ]

1.335
[Fp ]

>65°C
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.457
[Water Solubility ]

240ng/L at 20℃
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[LogP]

5.8 at 20℃
[CAS DataBase Reference]

85857-16-5(CAS DataBase Reference)
[EPA Substance Registry System]

Trimethoxy((perfluorohexyl)ethyl)silane (85857-16-5)
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

3265
[Hazard Note ]

Corrosive
[TSCA ]

No
[HazardClass ]

IRRITANT
[HS Code ]

29319090
Hazard InformationBack Directory
[Chemical Properties]

liquid
[Uses]

1H,1H,2H,2H-Perfluorooctyltrimethoxysilane, a functional material widely used to make material surface water-repellent[1]. Fluorosilane 1H,1H,2H,2H-perfluorooctyltrimethoxysilane could be coated onto the surface of BaTiO3 nanofibers by chemical reaction, which enhances their dispersion in poly(vinylidene fluoride) matrix[2].
[Flammability and Explosibility]

Nonflammable
[Synthesis]

1H,1H,2H,2H-Perfluorooctyltrimethoxysilane (PFOT) could be synthesized by a two-step method: after the hydrosilylation of trichlorosilane and 1H,1H,2H-perfluoro-1-octene (HPFO), the resulting product was then subjected to the alcoholic reaction with sodium methoxide to get the PFOT[1]. 
[References]

[1] Xianhong Zhang . "High dielectric constant and low dielectric loss hybrid nanocomposites fabricated with ferroelectric polymer matrix and BaTiO3 nanofibers modified with perfluoroalkylsilane." Applied Surface Science 305 (2014): Pages 531-538.
[2] Feihong Ye. "Effect of reaction conditions on one-step preparation of 1H,1H,2H,2H-Perfluorooctyltrimethoxysilane by catalytic hydrosilylation over RuCl3·3H2O catalysts." Journal of Industrial and Engineering Chemistry 110 (2022): Pages 405-413.
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