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ChemicalBook--->CAS DataBase List--->85116-37-6

85116-37-6

85116-37-6 Structure

85116-37-6 Structure
IdentificationMore
[Name]

(-)-Diisopinocampheyl chloroborane
[CAS]

85116-37-6
[Synonyms]

(-)-B-CHLORODIISOPINOCAMPHENYLBORANE
(-)-B-CHLORODIISOPINOCAMPHEYLBORANE
(-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE
(-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE
(-)-DIP-CHLORIDE
(-)-DIP-CHLORIDE(TM)
(-)-IPC2BCL
(-)-b-chlorodiisopinocampherylborane
(-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes
(-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes
(-)-Diisopinocampheylchloroborane, in hexanes, 2M solution
(-)-Diisopinocampheylchloroborane, in heptanes, 2M solution
(-)-DIP-CHLORIDE, 50-65 WT% IN HEPTANE
(-)-DIP-CHLORIDE, 60-75 WT% IN HEXANES
(-)-DIP CHLORIDE, 65-75 WT% IN ALPHA-PI&
(-)-dip-chloride tm solution
(-)-B-Chlorodiisopinocampheylborane
(-)-Diisopinocampheyl chloroborane
(-)-DIP-Chloride
(-)-SS-CHLORODIISOPINOCAMPHEYLBORANE
[EINECS(EC#)]

237-458-8
[Molecular Formula]

C20H34BCl
[MDL Number]

MFCD00074807
[Molecular Weight]

320.75
[MOL File]

85116-37-6.mol
Chemical PropertiesBack Directory
[Appearance]

solutio
[Melting point ]

52-56 °C(lit.)
[Boiling point ]

66-69°C
[density ]

0.954 g/mL at 25 °C
[refractive index ]

-51 ° (C=neat)
[Fp ]

82 °F
[storage temp. ]

2-8°C
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[BRN ]

5937756
[CAS DataBase Reference]

85116-37-6(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C,F+,N
[Risk Statements ]

R34:Causes burns.
R20/22:Harmful by inhalation and if swallowed .
R12:Extremely Flammable.
R10:Flammable.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R62:Possible risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[HazardClass ]

3/8
[PackingGroup ]

II
[HS Code ]

29319090
Hazard InformationBack Directory
[Chemical Properties]

solutio
[Uses]

Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
Spectrum DetailBack Directory
[Spectrum Detail]

(-)-Diisopinocampheyl chloroborane(85116-37-6)Raman
(-)-Diisopinocampheyl chloroborane(85116-37-6)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

85116-37-6(sigmaaldrich)
[TCI AMERICA]

(-)-B-Chlorodiisopinocampheylborane  (60% in Hexane, ca. 1.7mol/L)(85116-37-6)
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