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ChemicalBook--->CAS DataBase List--->85-02-9

85-02-9

85-02-9 Structure

85-02-9 Structure
IdentificationMore
[Name]

5,6-BENZOQUINOLINE
[CAS]

85-02-9
[Synonyms]

1-AZAPHENANTHRENE
5,6-BENZOQUINOLINE
BENZO[F]QUINOLINE
BETA-NAPHTHOQUINOLINE
NAPHTHOPYRIDINE
,6-Benzo[f]quinoline
5,6-benzo(f)quinoline
Benzoquinoline
5,6-Benzoquinoline, 99+%
b-naphthoquinoline
5,6-naphthoquinoline
[EINECS(EC#)]

201-582-0
[Molecular Formula]

C13H9N
[MDL Number]

MFCD00022235
[Molecular Weight]

179.22
[MOL File]

85-02-9.mol
Chemical PropertiesBack Directory
[Appearance]

BROWN CRYSTALLINE POWDER
[Melting point ]

89-91 °C
[Boiling point ]

349 °C (721 mmHg)
[density ]

1.1255 (rough estimate)
[refractive index ]

1.7270 (estimate)
[Fp ]

166 °C
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[Water Solubility ]

Insoluble in water
[form ]

Crystalline
[pka]

pK1: 5.00(+1) (25°C)
[color ]

Leaflets from H2O or pet ether
[Merck ]

1105
[CAS DataBase Reference]

85-02-9(CAS DataBase Reference)
[EPA Substance Registry System]

Benzo[f]quinoline (85-02-9)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R40:Limited evidence of a carcinogenic effect.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RTECS ]

DK1428000
[HS Code ]

29334990
[Toxicity]

mma-sat 50 mg/plate 50NNAZ 7,73,83
Hazard InformationBack Directory
[General Description]

Yellow crystals or white powder. Characteristic irritating odor.
[Reactivity Profile]

BENZO(F)QUINOLINE(85-02-9) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
[Air & Water Reactions]

Sensitive to prolonged exposure to air. Insoluble in water.
[Fire Hazard]

This compound is combustible.
[Chemical Properties]

BROWN CRYSTALLINE POWDER
[Uses]

As a reagent for the determination of cadmium which is pptd as (C13H9N)2H2(CdI4) from dil nitric or sulfuric acid solution in the presence of potassium iodide.
[Safety Profile]

Mutation data reported. Whenheated to decomposition it emits toxic fumes of NOx.
[Purification Methods]

Purify as 3,4-benzoquinoline above. The picrate has m 258.1-259o (from EtOH or H2O). [Albert et al. J Chem Soc 2240 1948, Beilstein 20 III/IV 4009, 20/8 V 220.]
Spectrum DetailBack Directory
[Spectrum Detail]

5,6-BENZOQUINOLINE(85-02-9)MS
5,6-BENZOQUINOLINE(85-02-9)1HNMR
5,6-BENZOQUINOLINE(85-02-9)13CNMR
5,6-BENZOQUINOLINE(85-02-9)IR1
5,6-BENZOQUINOLINE(85-02-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

5,6-Benzoquinoline, 99+%(85-02-9)
[Sigma Aldrich]

85-02-9(sigmaaldrich)
[TCI AMERICA]

Benzo[f]quinoline,>98.0%(T)(85-02-9)
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