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ChemicalBook--->CAS DataBase List--->777-37-7

777-37-7

777-37-7 Structure

777-37-7 Structure
IdentificationMore
[Name]

2-Chloro-5-nitrobenzotrifluoride
[CAS]

777-37-7
[Synonyms]

1-CHLORO-4-NITRO-2-(TRIFLUOROMETHYL)BENZENE
2-CHLORO-5-NITRO-A,A,A-TRIFLUOROTOLUENE
2-CHLORO-5-NITRO-ALPHA,ALPHA,ALPHA-TRIFLUOROTOLUENE
2-CHLORO-5-NITROBENZOTRIFLUORIDE
2-CHLORO-A,A,A-TRIFLUORO-5-NITROTOLUENE
4-Nitro-2-(trifluoromethyl)chlorobenzene
5-NITRO-2-CHLOROBENZOTRIFLUORIDE
TIMTEC-BB SBB007665
1-chloro-4-nitro-2-(trifluoromethyl)-benzen
2-(Trifluoromethyl)-4-nitrochlorobenzene
2-chloro-1-trifluoromethyl-5-nitro-benzene
2-chloro-5-nitro-α,α,α-trifluorotoluene
2-Chloro-alpha,alpha,alpha-trifluoro-5-nitrotoluene
3-(Trifluoromethyl)-4-chloronitrobenzene
4-Chloro-3-(trifluoromethyl)nitrobenzene
Benzene,1-chloro-4-nitro-2-(trifluoromethyl)-
Toluene, 2-chloro-alpha,alpha,alpha-trifluoro-5-nitro-
α,α,α-trifluoro-2-chloro-5-nitrotoluene
2-Chloro-5-nitrobenzotrifluoride 98%
2-Chloro-5-nitrobenzotrifluoride98%
[EINECS(EC#)]

212-287-1
[Molecular Formula]

C7H3ClF3NO2
[MDL Number]

MFCD00007296
[Molecular Weight]

225.55
[MOL File]

777-37-7.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colourless to light yellow liquid
[Melting point ]

22°C
[Boiling point ]

108 °C/10 mmHg (lit.)
[density ]

1.527 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.508(lit.)
[Fp ]

210 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder to lump to clear liquid
[color ]

White or Colorless to Yellow
[Specific Gravity]

1.527
[FreezingPoint ]

20.0 to 23.0 ℃
[BRN ]

2216169
[Exposure limits]

ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
[InChIKey]

HQROXDLWVGFPDE-UHFFFAOYSA-N
[CAS DataBase Reference]

777-37-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-chloro-4-nitro-2-(trifluoromethyl)-(777-37-7)
[EPA Substance Registry System]

777-37-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
[RIDADR ]

2810
[WGK Germany ]

3
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29039990
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Nitro-2-(trifluoromethyl)chlorobenzene(777-37-7).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear colourless to light yellow liquid
[Uses]

2-Chloro-5-nitrobenzotrifluoride is a polysubstituted organic fluorotoluene analogue. Its molecular structure has a reactive group chlorine atom at the 2-position and a nitro group at the 5-position. Therefore, the substance has high chemical reactivity and is widely used in the field of organic synthesis. It can be used to prepare asymmetric and symmetric diamine monomers containing trifluoromethyl groups, which in turn can be used to further prepare soluble polyimide, a multifunctional molecular material[1].
[References]

[1] SUN DAL KIM . Soluble polyimides with trifluoromethyl pendent groups[J]. Polymer, 2013. DOI:10.1016/j.polymer.2013.08.057.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Chloro-5-nitrobenzotrifluoride(777-37-7)1HNMR
2-Chloro-5-nitrobenzotrifluoride(777-37-7)Raman
2-Chloro-5-nitrobenzotrifluoride(777-37-7)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Chloro-5-nitrobenzotrifluoride, 96%(777-37-7)
[Alfa Aesar]

2-Chloro-5-nitrobenzotrifluoride, 98%(777-37-7)
[Sigma Aldrich]

777-37-7(sigmaaldrich)
[TCI AMERICA]

2-Chloro-5-nitrobenzotrifluoride,>97.0%(GC)(777-37-7)
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