| Identification | More | [Name]
ETHYL AZIDOACETATE | [CAS]
637-81-0 | [Synonyms]
AZIDOACETIC-ACID-ETHYL-ESTER
ETHYLAZIDACETATE
ETHYL AZIDOACETATE
azido-aceticaciethylester
ETHYL AZIDOACETATE SOLUTION, 25% IN ETHANOL
ETHYL AZIDOACETATE SOLUTION, 30% IN METHYLENECHLORIDE
ETHYL AZIDOACETATE SOLUTION, 25% IN TOLUENE
ethyl azidoacetate solution
Ethyl azidacetate 97%
Ethyl azidoacetate, GC 98%
2-Azidoacetic acid ethyl ester | [EINECS(EC#)]
211-301-3 | [Molecular Formula]
C4H7N3O2 | [MDL Number]
MFCD00190177 | [Molecular Weight]
129.12 | [MOL File]
637-81-0.mol |
| Chemical Properties | Back Directory | [Boiling point ]
44-46°C 2mm | [density ]
1.12g/ml | [refractive index ]
1.4330 to 1.4370 | [Fp ]
25 °C | [storage temp. ]
Refrigerator, under inert atmosphere | [solubility ]
Chloroform (Sparingly), Ethyl Acetate (Slightly) | [form ]
Oil | [color ]
Colourless to Pale Yellow | [BRN ]
4247209 | [CAS DataBase Reference]
637-81-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi,C | [Risk Statements ]
R1:Explosive when dry.
R40:Limited evidence of a carcinogenic effect.
R36/37/38:Irritating to eyes, respiratory system and skin .
R10:Flammable.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R38:Irritating to the skin.
R11:Highly Flammable. | [Safety Statements ]
S7:Keep container tightly closed .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S35:This material and its container must be disposed of in a safe way .
S36:Wear suitable protective clothing .
S47:Keep at temperature not exceeding ... E C (to be specified by the manufacturer) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN 1593 6.1/PG 3
| [WGK Germany ]
2
| [Hazard Note ]
Irritant/Corrosive | [HS Code ]
2929.90.5090 | [HazardClass ]
3 | [PackingGroup ]
III |
| Hazard Information | Back Directory | [Uses]
Ethyl Azidoacetate is an important organic substance that can undergo cyclisation reactions and is commonly used in the field of chemical synthesis.The condensation of 1-methyl-β-carboline-3-carbaldehyde with ethyl azidoacetate can be used to prepare 2-formylxanthine derivatives[1]. | [reaction suitability]
reaction type: click chemistry | [References]
[1] GLENN C. CONDIE Jan B. Synthesis of some fused β-carbolines including the first example of the pyrrolo[3,2-c]-β-carboline system[J]. Journal of Heterocyclic Chemistry, 2009, 41 4: 531-540. DOI:10.1002/jhet.5570410409. |
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