| Identification | More | [Name]
4-Chlorobenzyl bromide | [CAS]
622-95-7 | [Synonyms]
1-(Bromomethyl)-4-chlorobenzene
4CBB
4-CHLOROBENZYL BROMIDE
ALPHA-BROMO-4-CHLOROTOLUENE
Benzene, 1-(bromomethyl)-4-chloro-
Benzene,1-(bromomethyl)-4-chloro-
p-Chlorobenzyl bromide
4-Chlorobenzyl bromide, 98+%
à-bromo-4-chlorotoluene
4-Chlorobenzyl bromide 98% | [EINECS(EC#)]
210-760-7 | [Molecular Formula]
C7H6BrCl | [MDL Number]
MFCD00040714 | [Molecular Weight]
205.48 | [MOL File]
622-95-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White crystalline low melting solid | [Melting point ]
48-52 °C (lit.) | [Boiling point ]
107-108°C 8mm | [density ]
1.570±0.06 g/cm3(Predicted) | [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Chloroform, Dichloromethane (Slightly) | [form ]
Crystalline Low Melting Solid | [color ]
White | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Lachrymatory | [Detection Methods]
GC,NMR | [BRN ]
606497 | [InChIKey]
KQNBRMUBPRGXSL-UHFFFAOYSA-N | [CAS DataBase Reference]
622-95-7(CAS DataBase Reference) | [NIST Chemistry Reference]
4-Chlorobenzyl bromide(622-95-7) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1759 8/PG 2
| [WGK Germany ]
3
| [Hazard Note ]
Corrosive/Lachrymatory | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29049090 |
| Hazard Information | Back Directory | [Chemical Properties]
White crystalline low melting solid | [Uses]
4-Chlorobenzyl bromide is used as pharmaceutical intermediate. | [General Description]
4-Chlorobenzyl bromide undergoes carbonylation in the presence of dimer of chloro(1,5-cyclooctadiene)rhodium(I) to yield the corresponding phenylacetic acid. It can be synthesized by reacting 4-chlorobenzyl alcohol with bromodimethylsulfonium bromide (BDMS) It can also be synthesized by refluxing a mixture of 4-chlorobenzaldehyde, chlorotrimethylsilane, 1,1,3,3-tetramethyldisiloxane and lithium bromide. |
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