| Identification | More | [Name]
4-Nitrobenzyl alcohol | [CAS]
619-73-8 | [Synonyms]
4-NITROBENZYL ALCOHOL
4-NITROPHENYLCARBINOL
(4-NITROPHENYL)METHANOL
LABOTEST-BB LT01990178
NITROBENZYLALCOHOL(4-)
PARA NITRO BENZYL ALCOHOL
P-NITROBENZYL ALCOHOL
RARECHEM AL BD 0193
TIMTEC-BB SBB008259
1-Hydroxymethyl-4-nitrobenaene
4-(Hydroxymethyl)nitrobenzene
4-Nitrobenaylalcohol
4-nitro-benzenemethano
4-nitrobenzenemethanol
4-nitro-Benzenemethanol
Benzenemethanol, 4-nitro-
Benzenemethanol,4-nitro-
Benzyl alcohol, p-nitro-
Benzylalcohol,p-nitro-
p-(Hydroxymethyl)nitrobenzene | [EINECS(EC#)]
210-611-6 | [Molecular Formula]
C7H7NO3 | [MDL Number]
MFCD00007376 | [Molecular Weight]
153.14 | [MOL File]
619-73-8.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
92-94 °C(lit.)
| [Boiling point ]
185 °C12 mm Hg(lit.)
| [density ]
1.3585 (rough estimate) | [refractive index ]
1.5030 (estimate) | [Fp ]
180 °C
| [storage temp. ]
Store at RT. | [solubility ]
2g/l | [form ]
Crystalline Powder | [pka]
13.61±0.10(Predicted) | [color ]
Yellow | [Water Solubility ]
Soluble in water (2 mg/ml at 20°C). | [Detection Methods]
GC,NMR | [BRN ]
1424026 | [Dielectric constant]
22.0（20℃） | [InChIKey]
JKTYGPATCNUWKN-UHFFFAOYSA-N | [CAS DataBase Reference]
619-73-8(CAS DataBase Reference) | [NIST Chemistry Reference]
4-NO2-C6H4CH2OH(619-73-8) | [EPA Substance Registry System]
619-73-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C,F | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
R11:Highly Flammable. | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S16:Keep away from sources of ignition-No smoking . | [WGK Germany ]
3
| [RTECS ]
DP0657100
| [F ]
8 | [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29062900 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
4-Nitrobenzenemethanol is a potential building block in the synthesis of various pharmaceuticals. | [Definition]
ChEBI: A member of the class of benzyl alcohols that is benzyl alcohol substituted at the para-position by a nitro group. | [Synthesis Reference(s)]
Organic Syntheses, Coll. Vol. 3, p. 652, 1955
The Journal of Organic Chemistry, 55, p. 2968, 1990 DOI: 10.1021/jo00296a078
Tetrahedron Letters, 19, p. 4985, 1978 | [Purification Methods]
Crystallise the alcohol from EtOH and sublime it in vacuo. Purity should be at least 99.5%. Sublimed samples should be stored in the dark over anhydrous CaSO4 (Drierite). If the IR contains OH bands, then the sample should be resublimed before use. [Mohammed & Kosower J Am Chem Soc 93 2709 1979, Beilstein 6 IV 2611.] |
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