| Identification | More | [Name]
METHYL PHENYLPROPIOLATE | [CAS]
4891-38-7 | [Synonyms]
METHYL 3-PHENYLPROPIOLATE
METHYL-(PHENYLPROPIOLAT)
METHYL PHENYLPROPIOLATE
PHENYLPROPIOLIC ACID METHYL ESTER
2-Phenyl-1-carbomethoxyacetylene
2-Propynoic acid, 3-phenyl-, methyl ester
Methyl 3-phenyl-2-propynoate
Methyl 3-phenylpropynoate
Methyl phenylacetylenecarboxylate
Methyl phenylethynecarboxylate
Methyl phenylpropynoate
methylphenylpropynoate
Propiolic acid, 3-phenyl-, methyl ester
Propiolic acid, phenyl-, methyl ester
Methylphenylpropiolate,98+%
3-Phenyl-2-propynoicacidmethylester
3-Phenylpropargylic acid methyl ester
3-Phenylpropiolic acid methyl
Benzenepropiolic acid methyl ester
Phenylpropiolic acid methyl | [Molecular Formula]
C10H8O2 | [MDL Number]
MFCD00041685 | [Molecular Weight]
160.17 | [MOL File]
4891-38-7.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to pale yellow liquid | [Melting point ]
26°C | [Boiling point ]
109-112 °C/2 mmHg (lit.) | [density ]
1.086 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5590(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Liquid After Melting | [color ]
Clear colorless to pale yellow | [BRN ]
472813 | [InChIKey]
JFGWPXKGINUNDH-UHFFFAOYSA-N | [CAS DataBase Reference]
4891-38-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [HS Code ]
29163900 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to pale yellow liquid | [Uses]
Methyl phenylpropiolate may be used in the synthesis of:
- bicyclohexadienes
- cis-methyl cinnamate
- (E)-alkyl 3-(dialkoxyphosphoryl)-3-phenylacrylate derivatives
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 52, p. 4859, 1987 DOI: 10.1021/jo00231a007
Tetrahedron Letters, 21, p. 849, 1980 DOI: 10.1016/S0040-4039(00)71522-X | [General Description]
Organoiron carbonyl complexes are obtained by reacting methyl phenylpropiolate with Fe2(CO)9. |
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