| Identification | More | [Name]
TRICHLOROACETIC ANHYDRIDE | [CAS]
4124-31-6 | [Synonyms]
PERCHLOROACETIC ANHYDRIDE
TCAA
TRICHLOROACETIC ACID ANHYDRIDE
TRICHLOROACETIC ANHYDRIDE
trichloro-aceticacianhydride
Trichloroacetic acid anhydride (TCAA)
TRICHLOROACETIC ANHYDRIDE, TECH., 95%
TrichloroaceticAnhydride97%
Trichloroacetic Anhydride 97%
Acetic acid, trichloro-, anhydride
Bis(trichloroacetic)anhydride | [EINECS(EC#)]
223-925-3 | [Molecular Formula]
C4Cl6O3 | [MDL Number]
MFCD00000793 | [Molecular Weight]
308.76 | [MOL File]
4124-31-6.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Boiling point ]
139-141 °C/60 mmHg (lit.) | [density ]
1.69 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.484(lit.)
| [Fp ]
98-100°C/11mm | [solubility ]
Miscible with ether and acetic acid. | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Stability:]
Stable. Moisture sensitive-store under dry atmosphere. Incompatible with strong bases, strong oxidizing agents. | [Sensitive ]
Moisture Sensitive | [BRN ]
980355 | [Dielectric constant]
5.0 | [CAS DataBase Reference]
4124-31-6(CAS DataBase Reference) | [EPA Substance Registry System]
Acetic acid, trichloro-, anhydride (4124-31-6) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R22:Harmful if swallowed.
R35:Causes severe burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
2915907098 |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
Trichloroacetic Anhydride is used in organometallic reactions as well as oxadiazole containing 5-lipoxygenase activating protein inhibitors. | [Application]
Trichloroacetic anhydride can be used as a reagent for the generation of trichloroacetic acid esters and amides; the generation of trichloromethyl heterocycles; and the acylation of electron-rich olefins. | [General Description]
Trichloroacetic anhydride is reported to be an efficient derivatization reagent, since it produces stable derivatives having both a higher mass fragmentation pattern and lesser volatility than derivatives of trifluoroacetic anhydride (TFAA) or heptafluorobutyric anhydride (HFBA). The interaction of thymidine 5′-phosphate with trichloroacetic anhydride in dimethylformamide and acetonitrile in the presence of tertiary amines hs been studied. | [storage]
Trichloroacetic anhydride should be kept under inert gas; very reactive with water; corrosive. |
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