| Identification | More | [Name]
2-Fluorobenzonitrile | [CAS]
394-47-8 | [Synonyms]
2-CYANOFLUOROBENZENE
2-FLUOROBENZONITRILE
FLUOROBENZONITRILE
O-FLUOROBENZONITRILE
Benzonitrile, o-fluoro-
o-Cyanofluorobenzene
o-Fluorobenzonitrile 2-Fluorobenzonitrile
2-FLUOROBENZONITRILE 98% (GC)
2-Fluorobenzonitrile,99%
2-Fluorobenzonitrile 99%
2-Fluorbenzonitril
1-Fluoro-2-cyanobenzene | [EINECS(EC#)]
206-897-7 | [Molecular Formula]
C7H4FN | [MDL Number]
MFCD00001773 | [Molecular Weight]
121.11 | [MOL File]
394-47-8.mol |
| Chemical Properties | Back Directory | [Appearance]
colorless to light yellow liquid | [Melting point ]
-13.7 °C | [Boiling point ]
90 °C21 mm Hg(lit.)
| [density ]
1.116 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.505(lit.)
| [Fp ]
165 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform | [form ]
Liquid | [color ]
Clear colorless to light brownish | [Water Solubility ]
Insoluble | [Detection Methods]
HPLC | [BRN ]
2042184 | [InChIKey]
GDHXJNRAJRCGMX-UHFFFAOYSA-N | [CAS DataBase Reference]
394-47-8(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzonitrile, 2-fluoro-(394-47-8) | [EPA Substance Registry System]
394-47-8(EPA Substance) |
| Questions And Answer | Back Directory | [Synthesis]
Tetramethylammonium fluoride (TMAF) has been found to be an effective
fluorodenitration reagent. The good selectivity for the fluoroaromatic and not the
phenol has been attributed to the stability of ion pairing between nitrite and
tetramethylammonium ions. TMAF reacts with 2-nitrobenzonitrile to give a quantitative
conversion to 2-fluorobenzonitrile.
 |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,T,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing . | [RIDADR ]
3276 | [WGK Germany ]
3
| [Hazard Note ]
Toxic | [TSCA ]
T | [HazardClass ]
IRRITANT, IRRITANT-HARMFUL | [PackingGroup ]
III | [HS Code ]
29269095 |
| Hazard Information | Back Directory | [Chemical Properties]
colorless to light yellow liquid | [Uses]
2-Fluorobenzenenitrile (cas# 394-47-8) is a compound useful in organic synthesis. | [General Description]
2-Fluorobenzonitrile reacts with lithium N,N-dialkylaminoborohydride reagent to yield 2-(N,N-dialkylamino)benzylamines. |
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