| Identification | More | [Name]
CYCLOOCTENE OXIDE | [CAS]
286-62-4 | [Synonyms]
1,2-EPOXYCYCLOOCTANE
2-OXABICYCLO(6.1.0)NONANE
9-OXABICYCLO[6.1.0]NONANE
CYCLOOCTANE EPOXIDE
CYCLOOCTENE OXIDE
EPOXYCYCLOOCTANE
Cyclooctane, 1,2-epoxy-
Cyclooctane,1,2-epoxy-
Cycloocteneepoxide
Cyclooctenoxid
Epoxycyclooctane~2-Oxabicyclo[6.1.0]nonane
Cyclooctene oxide, GC 99%
1,2-EPOXYCYCLOOCTANE 97+%
9-Oxabicyclo[6.1.0]nonane, Epoxycyclooctane | [EINECS(EC#)]
206-010-3 | [Molecular Formula]
C8H14O | [MDL Number]
MFCD00005164 | [Molecular Weight]
126.2 | [MOL File]
286-62-4.mol |
| Chemical Properties | Back Directory | [Appearance]
COLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS | [Melting point ]
53-56 °C(lit.) | [Boiling point ]
55 °C5 mm Hg(lit.) | [density ]
0.9090 (rough estimate) | [refractive index ]
1.4540 (estimate) | [Fp ]
133 °F
| [storage temp. ]
2-8°C
| [solubility ]
soluble in Methanol | [form ]
powder to crystal | [color ]
White to Almost white | [BRN ]
103543 | [CAS DataBase Reference]
286-62-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 1325 4.1/PG 3
| [WGK Germany ]
2
| [F ]
10-21 | [HazardClass ]
4.1 | [PackingGroup ]
III | [HS Code ]
29109000 |
| Hazard Information | Back Directory | [Chemical Properties]
COLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 43, p. 1689, 1978 DOI: 10.1021/jo00403a015
Tetrahedron Letters, 27, p. 2617, 1986 DOI: 10.1016/S0040-4039(00)84599-2 | [Purification Methods]
It can be distilled in vacuum, and the solidified distillate can be sublimed in vacuum below 50o. It has a characteristic odour. [IR: Cope et al. J Am Chem Soc 74 5884 1952, cf trans-isomer: Cope et al. J Am Chem Soc 79 3905 1957, Reppe et al. Justus Liebigs Ann Chem 560 1 1948]. |
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