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ChemicalBook--->CAS DataBase List--->25054-53-9

25054-53-9

25054-53-9 Structure

25054-53-9 Structure
IdentificationMore
[Name]

Piperonyloyl chloride
[CAS]

25054-53-9
[Synonyms]

1,3-BENZODIOXOLE-5-CARBONYL CHLORIDE
3,4-(METHYLENEDIOXY)BENZOYL CHLORIDE
BUTTPARK 154\04-36
PIPERONYL CHLORIDE
PIPERONYLOYL CHLORIDE
TIMTEC-BB SBB003720
Benzo[d][1,3]dioxole-5-carbonyl chloride
1,3-Benzodioxole-5-carbonyl chloride (9CI)
Piperonoyl chloride
[Molecular Formula]

C8H5ClO3
[MDL Number]

MFCD00016904
[Molecular Weight]

184.58
[MOL File]

25054-53-9.mol
Chemical PropertiesBack Directory
[Appearance]

off-white to blue-grey crystalline powder
[Melting point ]

78-79 °C (lit.)
[Boiling point ]

155 °C/25 mmHg (lit.)
[density ]

1.3964 (estimate)
[storage temp. ]

Hygroscopic, Refrigerator, under inert atmosphere
[solubility ]

Chloroform (Slightly)
[form ]

Crystalline Powder
[color ]

Off-white to blue-gray
[Stability:]

Moisture Sensitive, reacts with Moisture in the air
[CAS DataBase Reference]

25054-53-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[Hazard Note ]

Corrosive
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29329900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Diethyl ether-->Tetrahydrofuran-->Thionyl chloride-->Dimethyl sulfoxide-->Diiodomethane-->Protocatechuic acid-->4-Iodobenzoyl chloride-->1-IODO-3,4-METHYLENEDIOXYBENZENE-->Terephthaloyl chloride
[Preparation Products]

1,3-BENZODIOXOLE-5-CARBOTHIOAMIDE-->6-(3,4-Methylenedioxyphenyl)-2H-pyran-2-one
Hazard InformationBack Directory
[Chemical Properties]

off-white to blue-grey crystalline powder
[Uses]

Piperonyloyl chloride is suitable for use in a kinetic study to evaluate the solvolysis rate constants of piperonyloyl chloride in 27 different solvents. It may be used in the synthesis of the following compounds:
  • 2-phenylbenzimidazoles
  • (Z)-3-hydroxy-1-(5-methoxy-2,2-dimethyl-2H-chromen-6-yl)-3-phenylprop-2-en-1-one
  • pongapinone A
  • 2-((1-(2-(N-(4-chlorophenyl)benzo[d][1,3]dioxole-5-carboxamido)ethyl)piperidin-4-yl)oxy)acetic acid phosphoric acid salt, inhibitor of platelet aggregation
  • justicidin B, the piscicidal components of Justicia Hayatai var. decumbens
  • piperazine derivatives
[General Description]

Piperonyloyl chloride is an acyl halide. It participates in the preparation of starting reagent (N-acyl indole), required for the synthesis of pyrrolophenanthridone alkaloids. Kinetic study of the solvolysis of piperonyloyl chloride in various pure and binary solvent mixtures has been proposed. Solvolysis reaction has been reported to proceed via electron-rich acyl transfer mechanism.
Spectrum DetailBack Directory
[Spectrum Detail]

Piperonyloyl chloride(25054-53-9)1HNMR
Piperonyloyl chloride(25054-53-9)IR
Piperonyloyl chloride(25054-53-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Piperonyloyl chloride, 98%(25054-53-9)
[Sigma Aldrich]

25054-53-9(sigmaaldrich)
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