| Identification | More | [Name]
Methyl nitroacetate | [CAS]
2483-57-0 | [Synonyms]
METHYL ALFA NITROACETATE
METHYL NITROACETATE
NITROACETIC ACID METHYL ESTER
Methyl 2-nitroacetate
Methyl a-nitroacetate
methyl2-nitroacetate
nitro-aceticacimethylester
Methylnitroacetate,98%
Methyl nitrozcetate | [EINECS(EC#)]
219-622-0 | [Molecular Formula]
C3H5NO4 | [MDL Number]
MFCD00075480 | [Molecular Weight]
119.08 | [MOL File]
2483-57-0.mol |
| Chemical Properties | Back Directory | [Appearance]
clear yellow liquid | [Boiling point ]
195-198 °C (lit.) | [density ]
1.294 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.425(lit.)
| [Fp ]
221 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Miscible with ethanol, ether and most organic solvents. | [form ]
clear liquid | [pka]
5.73±0.29(Predicted) | [color ]
Colorless to Light yellow | [Sensitive ]
Light Sensitive | [BRN ]
1758670 | [InChI]
InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3 | [InChIKey]
ALBSWLMUHHZLLR-UHFFFAOYSA-N | [SMILES]
C(OC)(=O)C[N+]([O-])=O | [CAS DataBase Reference]
2483-57-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Acetic acid, nitro-, methyl ester(2483-57-0) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
2
| [RTECS ]
AJ1093000
| [F ]
8 | [HS Code ]
29161995 |
| Hazard Information | Back Directory | [Chemical Properties]
clear yellow liquid | [Uses]
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606 |
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