| Identification | More | [Name]
Triethyl 2-fluoro-2-phosphonoacetate | [CAS]
2356-16-3 | [Synonyms]
2-FLUORO-2-PHOSPHONOACETIC ACID TRIETHYL ESTER
(DIETHOXYPHOSPHINYL)FLUOROACETIC ACID ETHYL ESTER
ETHYL (DIETHOXYPHOSPHINYL)FLUOROACETATE
TRIETHYL 2-FLUORO-2-PHOSPHONOACETATE
(R,S)-(Diethoxy-phosphoryl)-fluoro-aceticacidethylester
triethylphosphonofluoroacetate
TRIETHYL 2-FLUORO-2-PHOSPHONOACETATE, 96 %
2-Fluoro-2-phosphonoaceticacidtriethylester(FluorinatedHornerreagent)
Triethyl2-Fluoro-2-phosphoacetate
Triethyl-2-Fluoro-2-Phosphono
2-Fluoro-2-phosphonoacetic acid triethyl ester 96%
2-Fluoro-2-phosphonoaceticacidtriethylester97%
Triethyl-2-fluoro-phosphonoacetate
2-Phosphono-2-fluoroacetic acid triethyl ester
2-FLUORO-2-PHOSPHONOACETIC ACID TRIETHYL ESTER 95+%
ETHYL (DIETHOXYPHOSPHORYL)(FLUORO)ACETATE
2-Fluoro-2-(diethoxyphosphinyl)acetic acid ethyl ester
Fluoro(diethoxyphosphinyl)acetic acid ethyl ester | [EINECS(EC#)]
627-648-2 | [Molecular Formula]
C8H16FO5P | [MDL Number]
MFCD00134400 | [Molecular Weight]
242.18 | [MOL File]
2356-16-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Boiling point ]
75 °C0.01 mm Hg(lit.)
| [density ]
1.194 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.425(lit.)
| [Fp ]
165 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
1.194 | [BRN ]
1912161 | [CAS DataBase Reference]
2356-16-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,F | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [F ]
10-21 | [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT, FLAMMABLE | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
Reactant for:
- Diels-Alder reactions
- Biosynthesis of terpene
- Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates
- Synthesis of quinolones
- Horner-Wadsworth-Emmons asymmetric hydration
- Addition reactions and the subsequent application to click chemistry
- Asymmetric intermolecular Stetter reactions
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 60, p. 4730, 1995 DOI: 10.1021/jo00120a014 | [reaction suitability]
reaction type: C-C Bond Formation |
|
|