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ChemicalBook--->CAS DataBase List--->18479-58-8

18479-58-8

18479-58-8 Structure

18479-58-8 Structure
IdentificationMore
[Name]

2,6-Dimethyl-7-octen-2-ol
[CAS]

18479-58-8
[Synonyms]

2,6-DIMETHYL-7-OCTEN-2-OL
2,6-DIMETHYL-7-OCTENE-2-OL
7-OCTEN-2-OL, 2,6-DIMETHYL
DIHYDROMYRCENOL
DIMYRCETOL
FLORALYM(TM)
LYMOLENE
MYRCENOL
2,6-dimethyl-7-octen-2-o
2,6-Dimethyl-oct-7-en-2-ol
3,7-Dimethyl-1-octen-7-ol
Mircenol, 6,10-dihydro
DIHIDROMIRCENOL
Dihydromyrcenate
Dimyrcetal
Myrcetol
DIHYDROMYRCENOL 99+%
6(10)-dihydromyrcenol,2,6-dimethyl-7-octen-2-ol
dihydromyrcenol,6,10-dihydromyrcenol
Dihydro
[EINECS(EC#)]

242-362-4
[Molecular Formula]

C10H20O
[MDL Number]

MFCD00004474
[Molecular Weight]

156.27
[MOL File]

18479-58-8.mol
Chemical PropertiesBack Directory
[Boiling point ]

84 °C10 mm Hg(lit.)
[density ]

0.784 g/mL at 25 °C(lit.)
[vapor pressure ]

20Pa at 25℃
[refractive index ]

n20/D 1.443(lit.)
[Fp ]

170 °F
[form ]

neat
[pka]

15.31±0.29(Predicted)
[color ]

A colourless viscous liquid.
[Odor]

at 100.00 %. fresh citrus lime floral clean cologne weedy
[biological source]

synthetic
[Odor Type]

citrus
[Water Solubility ]

939mg/L at 20℃
[LogP]

3.25 at 40℃
[CAS DataBase Reference]

18479-58-8(CAS DataBase Reference)
[NIST Chemistry Reference]

7-Octen-2-ol, 2,6-dimethyl-(18479-58-8)
[EPA Substance Registry System]

18479-58-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

1
[RTECS ]

RH3420000
[Toxicity]

The acute oral LD50 value in rats was reported as 5.3 g/kg (4.5-6.1 g/kg) (Moreno, 1972). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1972)
Hazard InformationBack Directory
[Chemical Properties]

Dihydromyrcenol is a colorless liquid with a fresh citrus-like odor and a lavender note. It is obtained from 3,7-dimethyl-1,6- octadiene (citronellene), the pyrolysis product of cis-pinane and can be prepared by three different processes: (i) by addition of hydrogen chloride and subsequent hydrolysis of the resulting 2,6-dimethyl-2-chloro-7-octene; or (ii) by addition of formic acid and subsequent saponification of the resulting dihydromycrenyl formate; or (iii) by direct hydroxylation with 60–80% sulfuric acid.Dihydromyrcenol is used in fine fragrances as well as in soap and detergent perfumes for fresh lime and citrus-like floral notes.
[Occurrence]

Found in the leaf oils of Barosma venusta and in the oil of hops (Gildemeister & Hoffman, 1960)
[Uses]

Dihydromyrcenol is used in the fragrance industry for its fresh lime and citrus-like odor.
Dihydromyrcenol is a fragrance ingredient used in cosmetics, fine fragrances, shampoos, toilet soaps, and other toiletries as well as in non-cosmetic products such as household cleaners and detergents. Its worldwide use is greater than >1000 metric tons per year (IFRA, 2004). A colorless, somewhat viscous liquid that is a mixture of approximately 50% 2,6-dimethyl-7-octen-2-ol and 50% 2,6-dimethyl-7-octen-2-yl formate. It has apparently not been reported to occur in nature.
[Definition]

ChEBI: A monoterpenoid that is oct-7-en-2-ol substituted by methyl groups at positions 2 and 6 respectively.
[Preparation]

Prepared by adding hydrogen chloride to myrcene followed by hydrolysis under mild conditions (Bedoukian, 1967)
[General Description]

Methoxycarbonylation of dihydromyrcenol catalyzed by [PdCl2(PPh3)2]-SnCl2·2H2O-2PPh3 has been investigated. Dihydromyrcenol is a widely used fragrance ingredient and has been evaluated for developmental toxicity in pregnant Sprague-Dawley rats.
[Flammability and Explosibility]

Notclassified
[Solubility in organics]

Practically insoluble in water, soluble in alcohol and oils.
Spectrum DetailBack Directory
[Spectrum Detail]

Dihydromyrcenol(18479-58-8)MS
Dihydromyrcenol(18479-58-8)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

18479-58-8(sigmaaldrich)
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