| Identification | Back Directory | [Name]
(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE | [CAS]
180675-22-3 | [Synonyms]
2-methanidyl-1,3-dioxolane
Bromo(1,3-dioxolan-2-ylmethyl)magnesium
MagnesiuM,broMo(1,3-dioxolan-2-ylMethyl)-
(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE
magnesium,2-methanidyl-1,3-dioxolane,bromide
(1,3-dioxolan-2-ylmethyl)magnesium bromide solution
1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in THF
1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in 2-MeTHF
(1,3-Dioxolan-2-ylmethyl)magnesium bromide, 0.5M solution in THF
(1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide solution 0.5 M in THF
(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMI DE, 1.0M SOLUTION IN THF
(1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide, 0.5M solution in THF, AcroSeal | [Molecular Formula]
C4H7BrMgO2 | [MDL Number]
MFCD01321271 | [MOL File]
180675-22-3.mol | [Molecular Weight]
191.31 |
| Hazard Information | Back Directory | [Uses]
(1,3-Dioxolan-2-ylmethyl)magnesium bromide is a Grignard reagent that can be used to prepare:
- 3-[11C]-Propionaldehyde, a key intermediate for the synthesis of radiolabeled compound [11C]SN-38, wherein SN-38 is 7-ethyl-10-hydroxy camptothecin.
- 1-[(S)-2,2-Dimethyl-(1,3)-dioxolan-4-yl]-4-(1,3-dioxolan2-yl)-2-ol by reacting with D-glyceraldehyde, which is further used to synthesize unsaturated nucleosides.
- A bicyclo carboxylate intermediate, which is employed in the total synthesis of spirovibsanin A.
| [reaction suitability]
reaction type: Grignard Reaction |
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