| Identification | More | [Name]
3-CHLOROTHIOPHENE | [CAS]
17249-80-8 | [Synonyms]
3-CHLOROTHIOPHENE
3-thienyl chloride | [EINECS(EC#)]
605-636-8 | [Molecular Formula]
C4H3ClS | [MDL Number]
MFCD00043887 | [Molecular Weight]
118.58 | [MOL File]
17249-80-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow liquid | [Melting point ]
-62 °C | [Boiling point ]
137-139 °C(lit.) | [density ]
1.276 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.553(lit.)
| [Fp ]
99 °F
| [storage temp. ]
Flammables area | [form ]
Liquid | [color ]
Clear colorless to light yellow | [Specific Gravity]
1.276 | [BRN ]
105255 | [Exposure limits]
ACGIH: TWA 5 ppm (Skin)
OSHA: TWA 10 ppm(30 mg/m3)
NIOSH: IDLH 500 ppm; TWA 10 ppm(30 mg/m3) | [InChIKey]
QUBJDMPBDURTJT-UHFFFAOYSA-N | [CAS DataBase Reference]
17249-80-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
T,F,Xi | [Risk Statements ]
R61:May cause harm to the unborn child.
R10:Flammable.
R36:Irritating to the eyes.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
S7/9:Keep container tightly closed and in a well-ventilated place .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
-
| [Hazard Note ]
Irritant | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29339900 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow liquid | [Uses]
3-Chlorothiophene was used in the synthesis of poly(3-chlorothiophene) films by direct oxidation in mixed electrolytes of boron trifluoride diethyl etherate and trifluroacetic acid. | [Synthesis Reference(s)]
Journal of Heterocyclic Chemistry, 14, p. 281, 1977 DOI: 10.1002/jhet.5570140224 | [General Description]
Electrochemical homopolymerization of 3-chlorothiophene and copolymerization with 3-methylthiophene in ionic liquid has been investigated by potentiodynamic and galvanostat methods. |
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