| Identification | More | [Name]
4-ETHYNYLANILINE | [CAS]
14235-81-5 | [Synonyms]
1-AMINO-4-ETHYNYLBENZENE
4-AMINOPHENYLACETYLENE
4-ETHYNYLANILINE
4-ETHYNYLPHENYLAMINE
P-ETHYNYLANILINE
4-ethenylbenzenamine
4-Ethynyl aniline (4-aminophenylacetylene)
4-ETHYNYLANILINE 97%
Benzenamine, 4-ethynyl-(9CI) | [Molecular Formula]
C8H7N | [MDL Number]
MFCD00168824 | [Molecular Weight]
117.15 | [MOL File]
14235-81-5.mol |
| Chemical Properties | Back Directory | [Melting point ]
98-102 °C (dec.) (lit.) | [Boiling point ]
99-101 °C(Press: 13 Torr) | [density ]
1.05±0.1 g/cm3(Predicted) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Crystalline Powder | [pka]
3.11±0.10(Predicted) | [color ]
Yellow to brown | [BRN ]
2205181 | [InChIKey]
JXYITCJMBRETQX-UHFFFAOYSA-N | [CAS DataBase Reference]
14235-81-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37:Wear suitable protective clothing and gloves . | [WGK Germany ]
3
| [F ]
8-10-23 | [HS Code ]
29214990 |
| Questions And Answer | Back Directory | [Reaction]
4-Ethynylaniline, also known as p-ethynylaniline, is a terminal alkyne. Its synthesis using 2-methyl-3-butyn-2-ol (MEBYNOL) has been reported. The transition metal catalyzed polymerization of 4-ethynylaniline to afford poly(4-ethynylaniline) has been reported.[3]The impact of the surface functionalization with 4-ethynylaniline on the thermal behavior of multi-walled carbon nanotubes (MWNTs) and graphene has been investigated. | [Uses]
4-Ethynylaniline may be used in the synthesis of N-methyliminodiethyl 4-(4-ethynylphenyliminomethyl) benzeneboronate. It can also be used to prepare an acetylene ligand, HC2-NDI (NDI= 1,4,5,8-naphthalenediimide).It can be used as an alkyne component in a synthesis of indoles from nitroarenes in the presence of a palladium-phenantroline catalyst.
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| Hazard Information | Back Directory | [Chemical Properties]
White or light yellow solid | [Definition]
ChEBI: 4-ethynylaniline is a substituted aniline. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 59, p. 5818, 1994 DOI: 10.1021/jo00098a051 | [General Description]
4-Ethynylaniline, also known as p-ethynylaniline, is a terminal alkyne. Its synthesis using 2-methyl-3-butyn-2-ol (MEBYNOL) has been reported. The transition metal catalyzed polymerization of 4-ethynylaniline to afford poly(4-ethynylaniline) has been reported. The impact of the surface functionalization with 4-ethynylaniline on the thermal behavior of multi-walled carbon nanotubes (MWNTs) and graphene has been investigated. | [reaction suitability]
reaction type: click chemistry |
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