| Identification | More | [Name]
Diphenyl sulfide | [CAS]
139-66-2 | [Synonyms]
DIPHENYL SULFIDE
DIPHENYL SULPHIDE
PHENYL SULFIDE
PHENYL SULPHIDE
(Phenylsulfanyl)benzene
1,1’-thiobis(benzene)
1,1’-Thiobis[benzene]
1,1’-thiobis-benzen
1,1'-Thiobis(benzene)
Benzene, 1,1'-thiobis-
benzene,1,1’-thiobis
Diphenyl monosulfide
Diphenyl thioether
Diphenylmercaptan
Diphenylthiamethane
diphenylthioether
Phenylthiobenzene
Sulfide, diphenyl
sulfide,diphenyl
Diphenyl sulphide 99% | [EINECS(EC#)]
205-371-4 | [Molecular Formula]
C12H10S | [MDL Number]
MFCD00003064 | [Molecular Weight]
186.27 | [MOL File]
139-66-2.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
-40 °C (lit.) | [Boiling point ]
296 °C (lit.) | [density ]
1.113 g/mL at 20 °C(lit.)
| [vapor pressure ]
0.01 hPa (25 °C) | [refractive index ]
n20/D 1.6327(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Store below +30°C. | [solubility ]
Soluble in ether, benzene, carbon disulphide. | [form ]
Liquid | [color ]
Clear colorless to light yellow | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [Water Solubility ]
insoluble | [Sensitive ]
Stench | [Merck ]
14,7314 | [BRN ]
1907932 | [InChIKey]
LTYMSROWYAPPGB-UHFFFAOYSA-N | [LogP]
4.63 at 20℃ | [CAS DataBase Reference]
139-66-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Diphenyl sulfide(139-66-2) | [EPA Substance Registry System]
139-66-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,N | [Risk Statements ]
R22:Harmful if swallowed.
R38:Irritating to the skin.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 3082 9/PG 3
| [WGK Germany ]
3
| [RTECS ]
SX2275000
| [F ]
13 | [Hazard Note ]
Harmful/Stench | [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29309090 | [Toxicity]
LD50 orally in rats: 0.49 ml/kg (Smyth) |
| Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
Diphenyl Sulfide is an aromatic organosulfur compound. Diphenyl Sulfide is metabolite of the fungicide Edifenphos as well as a potential Impurity of Fenticonazole Nitrate (F279250). | [Definition]
ChEBI: An aryl sulfide that consists of two phenyl groups connected by a sulphur atom. | [Synthesis Reference(s)]
Chemical and Pharmaceutical Bulletin, 35, p. 1770, 1987 DOI: 10.1248/cpb.35.1770 | [Flammability and Explosibility]
Notclassified | [Purification Methods]
Wash the sulfide with aqueous 5% NaOH, then water. Dry it with CaCl2, then with sodium. The sodium is filtered off, and the diphenyl sulfide is distiiled under reduced pressure. [Beilstein 2 H 299, 6 IV 1488.] |
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