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ChemicalBook--->CAS DataBase List--->133730-34-4

133730-34-4

133730-34-4 Structure

133730-34-4 Structure
IdentificationMore
[Name]

2,4-Dimethoxybenzeneboronic acid
[CAS]

133730-34-4
[Synonyms]

2,4-DIMETHOXYBENZENEBORONIC ACID
2,4-DIMETHOXYPHENYLBORONIC ACID
AKOS BRN-0063
RARECHEM AH PB 0099
2,4-DIMETHOXYBENZENEBORONIC ACID,98+%
2,4-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride)
2,4-Dimethoxyphenylboronic acid ,98%
[EINECS(EC#)]

679-695-3
[Molecular Formula]

C8H11BO4
[MDL Number]

MFCD01074590
[Molecular Weight]

181.98
[MOL File]

133730-34-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to beige or pink moist powder
[Melting point ]

125-127 °C (lit.)
[Boiling point ]

361.1±52.0 °C(Predicted)
[density ]

1.19±0.1 g/cm3(Predicted)
[storage temp. ]

0-6°C
[solubility ]

soluble in Methanol
[form ]

powder to crystal
[pka]

8.98±0.58(Predicted)
[color ]

White to Dark green
[Detection Methods]

HPLC,NMR
[BRN ]

4744213
[CAS DataBase Reference]

133730-34-4(CAS DataBase Reference)
Questions And AnswerBack Directory
[Uses]

2,4-Dimethoxyphenylboronic acid can be used:

?  As a reactant in meatal-catalyzed Suzuki?Miyaura cross-coupling reaction.

?  To prepare hydroxy(trimethoxy)phenanthrene by cross-coupling with bromo(benzyloxy)methoxybenzaldehyde followed by condensation and debenzylation reaction.

? To synthesize 2,4-dimethoxy-1-(trifluoromethyl)benzene via Cu-catalyzed trifluoromethylation reaction.

[Uses]

Reactant for:

? Suzuki-Miyaura and Negishi couplings.

Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

3
[Hazard Note ]

Irritant/Keep Cold
[HazardClass ]

IRRITANT
[HS Code ]

29319099
Hazard InformationBack Directory
[Chemical Properties]

white to beige or pink moist powder
Spectrum DetailBack Directory
[Spectrum Detail]

2,4-Dimethoxybenzeneboronic acid(133730-34-4)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,4-Dimethoxybenzeneboronic acid, 97%(133730-34-4)
[Alfa Aesar]

2,4-Dimethoxybenzeneboronic acid, 98%(133730-34-4)
[Sigma Aldrich]

133730-34-4(sigmaaldrich)
[TCI AMERICA]

2,4-Dimethoxyphenylboronic Acid  (contains varying amounts of Anhydride)(133730-34-4)
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