| Identification | More | [Name]
VANADIUM(IV) OXIDE | [CAS]
12036-21-4 | [Synonyms]
VANADIUM DIOXIDE
VANADIUM(IV) OXIDE
VANADIUM OXIDE
VANADIUM TETRAOXIDE
Vanadium oxide (VO2)
vanadiumoxide(vo2)
VO2
Vanadium(Ⅳ)oxide
VANADIUM(IV) OXIDE, 99.9%
VANADIUM(IV) OXIDE 98+%
VANADIUM (IV) OXIDE 99+%
Vanadium(IV)oxide(metalsbasis)
Vanadium tetroxide
Vanadium(IV) oxide, 99.90%
Vanadium(IV) oxide, 99% (metals basis)
Vanadium(IV)dioxide | [EINECS(EC#)]
234-841-1 | [Molecular Formula]
O2V | [MDL Number]
MFCD00049702 | [Molecular Weight]
82.94 | [MOL File]
12036-21-4.mol |
| Chemical Properties | Back Directory | [Appearance]
Blue-black powder. Insoluble in water; soluble in alkalies and acids. | [Melting point ]
1967°C | [density ]
4.339 g/mL at 25 °C(lit.)
| [solubility ]
insoluble in H2O; soluble in acid solutions, alkaline solutions | [form ]
Powder | [color ]
black | [Specific Gravity]
4.339 | [Water Solubility ]
Insoluble in water. | [Crystal Structure]
MoO2 type | [crystal system]
Monoclinic | [Space group]
P21/c | [Lattice constant]
| a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 0.53528 | 0.45378 | 0.53825 | 90 | 115.208 | 90 | 0.1183 |
| [Exposure limits]
NIOSH: Ceiling 0.05 mg/m3 | [CAS DataBase Reference]
12036-21-4(CAS DataBase Reference) | [EPA Substance Registry System]
Vanadium oxide (VO2) (12036-21-4) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN3285 | [WGK Germany ]
3
| [F ]
10-23 | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
28253090 |
| Questions And Answer | Back Directory | [Description]
Vanadium (IV) dioxide is a kind of inorganic compound with its
chemical formula being VO2. It can undergo a phase transition at a
normal temperature (~66 °C). Its electrical resistivity and opacity
can also change several fold. These special properties make it have
many applications. For example, it can be used in chemical sensors,
energy-conserving coatings, transparent conductors and switching
materials. It can also be used as a stationary optical shutter,
optical modulators, cameras and data storage. Moreover, it can be
applied to the missile guidance system due to its infrared
modulation capability. It can also be used to make thin films which
have been used in electro-optical switches, micro-optical switch,
passive smart radiators and sunshields for spacecraft. It can also
be used in phase change computing and memory. | [References]
https://en.wikipedia.org/wiki/Vanadium(IV)_oxide
https://www.alfa.com/en/catalog/022957/
|
| Hazard Information | Back Directory | [Chemical Properties]
Blue-black powder. Insoluble in water; soluble in alkalies and acids. | [Chemical Properties]
Vanadium(IV) Oxide (vanadium dioxide, VO2) is a blue-black solid, having a distorted rutile (TiO2) structure. It can be prepared from the reaction of V2O5 at the melting point with sulfur or carbonaceous reductants such as sugar or oxalic acid. The dioxide slowly oxidizes in air. Vanadium dioxide dissolves in acids to give the stable (VO)2+ ions and in hot alkalies to yield vanadate(IV) species, eg, (HV2O5)?. | [Uses]
Vanadium(IV) oxide is used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It acts as a stationary optical shutter, optical modulators, cameras and data storage. As infrared modulators, it is used for the missile guidance systems. Thin films made up of vanadium dioxide find applications in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft. | [Definition]
ChEBI: Vanadium dioxide is a vanadium oxide. | [Hazard]
Toxic and irritating. | [Flammability and Explosibility]
Nonflammable | [reaction suitability]
reagent type: catalyst
core: vanadium |
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