| Identification | More | [Name]
2-Benzyl-2-(dimethylamino)-4'-morpholinobutyrophenone | [CAS]
119313-12-1 | [Synonyms]
2-BENZYL-2-(DIMETHYLAMINO)-4'-MORPHOLINOBUTYROPHENONE
TIMTEC-BB SBB006931
2-(dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-1-butanon
2-benzyl-2-(dimethylamino)-4'-morpholino-butyroph
2-Benzyl-2-(Dimethylamino)-1-[4-(4-Morpholinyl)phenyl]-1-Butanone
Lancure369
1-Butanone, 2-(dimethylamino)-1-4-(4-morpholinyl)phenyl-2-(phenylmethyl)-
2-Benzyl-2-dimethylamino-4′-morpholinobutyrophenon
2-Benzyl-2-dimethylamino-1-(4-morpholino-phenyl)-1-butanone
IHT-PI 910
1-(4-Morpholinophenyl)-2-(dimethylamino)-2-benzyl-1-butanone
IC-369
Irgacure 369
N,N-Dimethyl-α-ethyl-α-benzyl-β-oxo-4-(4-morpholinyl)benzeneethanamine
α-(Dimethylamino)-α-benzyl-4'-morpholinobutyrophenone | [EINECS(EC#)]
404-360-3 | [Molecular Formula]
C23H30N2O2 | [MDL Number]
MFCD00191775 | [Molecular Weight]
366.5 | [MOL File]
119313-12-1.mol |
| Chemical Properties | Back Directory | [Melting point ]
116-119 °C (lit.) | [Boiling point ]
528.8±50.0 °C(Predicted) | [density ]
1.094±0.06 g/cm3(Predicted) | [vapor pressure ]
0-0.01Pa at 25-95℃ | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
3240 in mg/100g standard fat at 20 ℃ | [form ]
powder to crystal | [pka]
7.04±0.50(Predicted) | [color ]
Light orange to Yellow to Green | [Water Solubility ]
5.9mg/L at 20℃ | [InChIKey]
UHFFVFAKEGKNAQ-UHFFFAOYSA-N | [LogP]
2.91 at 25℃ | [CAS DataBase Reference]
119313-12-1(CAS DataBase Reference) | [EPA Substance Registry System]
119313-12-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
N | [Risk Statements ]
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3077 9/PG 3
| [WGK Germany ]
2
| [RTECS ]
EL7755000
| [HazardClass ]
9 | [PackingGroup ]
III | [HS Code ]
29349990 |
| Hazard Information | Back Directory | [Chemical Properties]
Light yellow solid | [Uses]
DBMP can be used as a dopant to dope silicone elastomer for the formation of 3D biocompatible scaffolds. It can also be used in two photon polymerization for the micro-fabrication of 3D hydrogels for potential biomedical and tissue engineering applications. | [Uses]
UV solidify ink and coating | [General Description]
2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone (DBMP) is a photoinitiator that acts at near UV and visible range. It can be incorporated into the polymeric matrix, which upon UV irradiation forms radicals by radical chain polymerization. | [Synthesis]
General procedure for the synthesis of 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone from 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone and morpholine: 2-benzyl-2-dimethylamino-1-P-fluorophenyl-1-butanone was dissolved in ethylene dichloride and transferred to a four-necked flask. Morpholine (139.6 g, 1.6 mol) and 1 L of dichloroethane were added and the reaction was heated to reflux state. The reaction progress was monitored by TLC or high performance liquid chromatography (HPLC). After completion of the reaction, the reaction was cooled to room temperature, the reaction mixture was washed by adding 200 ml of water and stirred for 30 min. After standing and layering, the organic phase was separated. The solvent was recovered by distillation under reduced pressure to obtain the crude product. The crude product was recrystallized from 440 ml of ethanol to give 117.2 g of a light yellow solid product with a melting point of 115-116 °C, an overall yield of 80% and a purity of 99.3%. | [References]
[1] Patent: CN105384707, 2016, A. Location in patent: Paragraph 0003; 0034 |
|
|