| Identification | More | [Name]
Lithium sulfate | [CAS]
10377-48-7 | [Synonyms]
LITHIUM SULFATE
LITHIUM SULPHATE
Dilthium sulfate
Li2SO4
Lithiophor
Lithium sulfate (2:1)
Lithium sulfate, alpha
Lithium-Duriles
lithiumsulfate(2:1)
lithiumsulfateanhydrous
Sulfuric acid lithium salt
Sulfuric acid, dilithium salt
Sulfuric acid, lithium salt (1:2)
Sulfuricacid,dilithiumsalt
sulfuricacid,lithiumsalt(1:2)
LITHIUM SULPHATE MONO.
LITHIUM SULFATE ANHYDROUS PHOTOGRAPHIC*G RADE
LITHIUM SULFATE, 99.99+%
LITHIUM SULFATE, >= 98.5%
Lithium sulfate monohydrate, ReagentPlus®,, 99% | [EINECS(EC#)]
233-820-4 | [Molecular Formula]
Li2O4S | [MDL Number]
MFCD00011086 | [Molecular Weight]
109.94 | [MOL File]
10377-48-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White crystalline powder | [Melting point ]
845 °C (lit.) | [density ]
2.22 g/mL at 25 °C(lit.)
| [refractive index ]
1.465 | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
absolute ethanol: insoluble(lit.) | [form ]
Powder | [pka]
2.08[at 20 ℃] | [color ]
White | [PH]
6.0-9.0 (25℃, 2M in H2O) | [Water Solubility ]
25.7 g/100 mL (25 ºC) | [Sensitive ]
Hygroscopic | [λmax]
λ: 260 nm Amax: 0.08
λ: 280 nm Amax: 0.04 | [Merck ]
14,5541 | [Stability:]
Hygroscopic | [CAS DataBase Reference]
10377-48-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Lithium sulfate(10377-48-7) | [EPA Substance Registry System]
10377-48-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves . | [WGK Germany ]
1
| [RTECS ]
OJ6419000
| [TSCA ]
Yes | [HS Code ]
28332990 | [Toxicity]
mammal (species unspecified),LD50,intramuscular,560mg/kg (560mg/kg),Farmakologiya i Toksikologiya Vol. 9, Pg. 113, 1974. |
| Questions And Answer | Back Directory | [Chemical Properties]
Lithium sulfate is a colorless monoclinic or hexagonal crystalline solid. It is the lithium salt of sulfuric acid. Although lithium sulfate solution is prepared in a large quantity as an intermediate in the spodumene-sulfuric acid process, the pure compound has only limited industrial use. It is used in small quantities in molten salt baths for the chemical strengthening of glass.
The dissolved lithium sulfate is converted into lithium carbonate by adding sodium carbonate (NaCO3).The sodium replaces the lithium in the sulfate compound.This reaction works this way because sodium is more reactive than lithium.
| [Uses]
Lithium sulfate is used in making a special type of high strength glass. It
also is used in medicine as an antidepressant. | [Preparation]
Lithium sulfate is prepared by neutralization of lithium hydroxide or lithium carbonate with sulfuric acid followed by crystallization:
2LiOH + H2SO4 → Li2SO4 + H2O
Li2CO3 + H2SO4 → Li2SO4 + CO2 + H2O
The product obtained from crystallization in a concentrated solution is the monohydrate, Li2SO4•H2O. Anhydrous salt is obtained by heating the monohydrate in a vacuum.
|
| Hazard Information | Back Directory | [Definition]
ChEBI: A metal sulfate in which the counterion is lithium and the ratio of lithium to sulfate is 2:1. | [Flammability and Explosibility]
Nonflammable | [Purification Methods]
Crystallise it from H2O (4mL/g) by partial evaporation, and dry it above 130o in vacuo. |
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