| Identification | More | [Name]
Cinnamyl acetate | [CAS]
103-54-8 | [Synonyms]
3-PHENYL-2-PROPEN-1-YL ACETATE
3-PHENYLALLYL ACETATE
ACETIC ACID CINNAMYL ESTER
CINNAMYL ACETATE
FEMA 2293
PHENYL ALLYL ACETATE
(2E)-3-Phenyl-2-propenyl acetate
2-Propen-1-ol,3-phenyl-,acetate
3-phenyl-2-propen-1-oacetate
3-Phenyl-2-propen-1-ol acetate
3-phenyl-2-propen-1-olacetate
3-Phenyl-2-propenyl acetate
cinnamyl
Cinnamyl alcohol, acetate
cinnamylalcohol,acetate
gamma-Phenylallyl acetate
gamma-phenylallylacetate
N-Cinnamoyl-N-phenylhydroxylam
N-Cinnamoyl-N-phenylhydroxylamine
CINNAMYL ACETATE 98+% FCC | [EINECS(EC#)]
203-121-9 | [Molecular Formula]
C11H12O2 | [MDL Number]
MFCD00008722 | [Molecular Weight]
176.21 | [MOL File]
103-54-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to pale yellowish liquid | [Melting point ]
30 °C | [Boiling point ]
265 °C(lit.)
| [density ]
1.057 g/mL at 25 °C
| [vapor pressure ]
16Pa at 20℃ | [FEMA ]
2293 | [refractive index ]
n20/D 1.541(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
2-8°C | [solubility ]
alcohol: soluble(lit.) | [form ]
neat | [color ]
Colorless to Light yellow | [Odor]
at 100.00 %. sweet floral spicy balsam cinnamon | [biological source]
synthetic | [Odor Type]
spicy | [Water Solubility ]
176.2mg/L(temperature not stated) | [JECFA Number]
650 | [LogP]
2.7 at 35℃ | [Uses]
Perfumery (fixative), flavoring. | [CAS DataBase Reference]
103-54-8(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Propen-1-ol, 3-phenyl-, acetate(103-54-8) | [EPA Substance Registry System]
103-54-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36:Irritating to the eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
1
| [RTECS ]
GE2275000
| [HS Code ]
29153900 | [Safety Profile]
Moderately toxic by
ingestion and intraperitoneal routes. A skin
irritant. Combustible liquid. When heated to
decomposition it emits acrid smoke and
fumes. See also ALLYL COMPOUNDS. | [Toxicity]
The acute oral LD50 in rats was reported to be 3.3 g/kg (2.9-3.7 g/kg) (Moreno, 1972). The acute dermal LD50 was reported to be > 5 g/kg in the rabbit (Moreno, 1972). |
| Hazard Information | Back Directory | [Chemical Properties]
Cinnamyl acetate has a characteristic balsamic-floral odor and burning, sweet taste reminiscent of pineapple. The ester
obtained from natural cinnamyl alcohol exhibits a more delicate (hyacinth–jasmine-like) note. | [Chemical Properties]
clear colorless to pale yellowish liquid | [Occurrence]
Reported found in melon, starfruit, tarragon and litchi. | [Application]
Cinnamyl acetate is used as a modifier for Cinnamic alcohol and as a warm-spicy-floral note in heavy florals, Hyacinth, etc. It can also introduce warmth to a Rose composition at a discrete concentration level. Used in flavor compositions for imitation Apple, Apricol, Berry, Cherry, Cinnamon, Cassia, Grape, Peach, Pineapple, Quince, Vanilla, etc.
| [Definition]
ChEBI: An acetate ester resulting from the formal condensation of cinnamyl alcohol with acetic acid. Found in cinnamon leaf oil. | [Preparation]
By direct esterification of cinnamic alcohol with acetic acid (or anhydride) under azeotropic conditions (Arctander, 1969). | [Taste threshold values]
Taste characteristics at 15 ppm: sweet, spicy, floral, cinnamon and honey with a tutti-fruitti nuance. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 90, p. 5518, 1968 DOI: 10.1021/ja01022a034 | [General Description]
Cinnamyl acetate is a fragrance ingredient. Palladium catalyzed allylic alkylation of cinnamyl acetate using sodium diethyl 2-methylmalonate and novel ferrocenyl Schiff base has been investigated. | [Flammability and Explosibility]
Nonflammable |
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