TRIETHYLSILANOL synthesis
- Product Name:TRIETHYLSILANOL
- CAS Number:597-52-4
- Molecular formula:C6H16OSi
- Molecular Weight:132.28
617-86-7
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597-52-4
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$44.50/1g
Yield:597-52-4 100%
Reaction Conditions:
with 5%-palladium/activated carbon;water in ethyl acetate
Steps:
Triethylsilanol
To the suspension of Pd/C (5 wt %, 10 mg), water (465 μL, 25.8 mmol, 3.0 equiv) and EtOAc (10 mL) was added triethylsilane (1.0 g, 1.37 mL, 8.60 mmol, 1.0 equiv). Immediately after the addition of triethylsilane H2-formation 8 was observed. After thebubbling ended, the reaction mixture was filtered through a small pad of alumina(neutral) column eluted with EtOAc (20 mL). The filtrate was concentrated in vacuum to afford product 7 as a colorless oil (1.15 g, 8.6 mmol, Quant).
References:
Tuokko, Sakari;Pihko, Petri M. [Synlett,2016,vol. 27,# 11,art. no. ST-2016-B0177-L,p. 1649 - 1652] Location in patent:supporting information
617-86-7
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124-38-9
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597-52-4
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994-49-0
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590-29-4
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994-30-9
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597-52-4
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$44.50/1g
617-86-7
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$9.00/5g
597-52-4
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1333-74-0
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