Ethylene glycol monoethyl ether acetate synthesis
- Product Name:Ethylene glycol monoethyl ether acetate
- CAS Number:111-15-9
- Molecular formula:C6H12O3
- Molecular Weight:132.16
110-80-5
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108-05-4
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111-15-9
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$14.00/25ml
Yield:111-15-9 100%
Reaction Conditions:
with dilithium tetra(tert-butyl)zincate in toluene at 0; for 1 h;Inert atmosphere;
Steps:
General procedure: A typical procedure was as follows. Vinyl acetate (5.0mmol), benzyl alcohol (1.0mmol), and solvent (2.0mL) were added to a glass ampoule which had been degassed and filled with nitrogen. A solution of TBZL (0.1mmol) in THF was added under a nitrogen atmosphere to the ampoule placed in a constant-temperature bath. Then the mixture was kept at 25 or 0°C and stirred. After a prescribed period, the mixture was diluted with CDCl3 and transformed in a NMR tube. Conversion of the reaction was determined by 1H NMR at 400MHz.
References:
Oshimura, Miyuki;Oda, Yuki;Kondoh, Keita;Hirano, Tomohiro;Ute, Koichi [Tetrahedron Letters,2016,vol. 57,# 19,p. 2070 - 2073]
110-80-5
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105-46-4
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111-15-9
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3100-09-2
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111-15-9
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129751-10-6
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111-15-9
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110-80-5
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497-26-7
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111-15-9
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141-78-6
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