3,4-METHYLENEDIOXYBENZYLIDENE ANILINE synthesis
- Product Name:3,4-METHYLENEDIOXYBENZYLIDENE ANILINE
- CAS Number:27738-39-2
- Molecular formula:C14H11NO2
- Molecular Weight:225.24
495-76-1
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98-95-3
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27738-39-2
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$108.00/10g
Yield:27738-39-2 95%
Reaction Conditions:
with ruthenium(III) chloride trihydrate;potassium carbonate at 130; for 24 h;Sealed tube;Inert atmosphere;
Steps:
4.3. The procedure of two-step route. Step 1
General procedure: A mixture of aryl alcohol (3.0mmol), nitrobenzene (1.0mmol), RuCl3·3H2O (3.0mol%) and K2CO3 (1.0mmol) was stirred at 130°C for 24h in a sealed tube under a nitrogen atmosphere. After cooling to room temperature, water (10mL) was added and the aqueous solution was extracted with dichloromethane (3×10mL). The combined extracts were dried with anhydrous Na2SO4, the solvent was removed and the crude product was purified by a short flash chromatography column.
References:
Tan, Da-Wei;Li, Hong-Xi;Young, David James;Lang, Jian-Ping [Tetrahedron,2016,vol. 72,# 29,p. 4169 - 4176]
495-76-1
294 suppliers
$15.00/5g
62-53-3
677 suppliers
$10.00/1g
27738-39-2
24 suppliers
$108.00/10g
495-76-1
294 suppliers
$15.00/5g
98-95-3
28 suppliers
$14.00/25g
27738-39-2
24 suppliers
$108.00/10g
62-53-3
677 suppliers
$10.00/1g
495-76-1
294 suppliers
$15.00/5g
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27738-39-2
24 suppliers
$108.00/10g