2,2,3-TRICHLOROPROPIONITRILE synthesis
- Product Name:2,2,3-TRICHLOROPROPIONITRILE
- CAS Number:813-74-1
- Molecular formula:C3H2Cl3N
- Molecular Weight:158.41
107-13-1
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813-74-1
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Yield:813-74-1 412.0 g (92%)
Steps:
I.a a.
a. α,α,β-Trichloropropanonitrile Acrylonitrile (150.0 g; 2.82 moles) is chlorinated with chlorine gas (>200.2 g; >5.64 moles) for approximately 8 hours. The reaction temperature is maintained at 25°-30° C. by external water cooling. The progress of the reaction is monitored by GLC analysis until essentially a single peak is obtained in the chromatogram. At this point, the flow of chlorine is discontinued and the reaction mixture is degassed by sparging with a vigorous nitrogen flow for one hour. The crude liquid product is distilled to yield 412.0 g (92%) of α,α,β-trichloropropanonitrile (bp 100° C. ? 125 mm Hg).
References:
US5039702,1991,A
542-76-7
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813-74-1
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920-37-6
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10151-09-4
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