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(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)???

(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)???
(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)??? ??? ???
?? ??:
53531-34-3
???:
(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)???
???(??):
(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)???
???:
(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL
???(??):
Pirkle's alcohol;(-)-2,2,2-Trifluoro-1-(9-anthryl)ethanol;(1R)-1-(9-Anthryl)-2,2,2-trifluoroethanol;(R)-2,2,2-Trifluoro-1-(9-anthracenyl)ethanol;ALPHA-(TRIFLUOROMETHYL)-9-ANTHRACENEMETHANOL;(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL;(R)-(-)-1-(9-ANTHRYL)-2,2,2-TRIFLUOROETHANOL;(R)-α-(Trifluoromethyl)-9-anthracenemethanol;(1R)-1-anthracen-9-yl-2,2,2-trifluoroethanol;(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)ETHANOL 98+%
CBNumber:
CB4117670
???:
C16H11F3O
??? ??:
276.26
MOL ??:
53531-34-3.mol
MSDS ??:
SDS

(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)??? ??

???
132-135 °C(lit.)
?? ?
423.1±45.0 °C(Predicted)
??
1.2578 (estimate)
???
-30.5 ° (C=1, CHCl3)
?? ??
Keep in dark place,Inert atmosphere,Room temperature
?? ?? (pKa)
11.91±0.30(Predicted)
??? ??
powder to crystal
??
White to Light yellow to Green
optical activity
[α]25/D 30°, c = 6.0 in chloroform
BRN
4695163
CAS ??????
53531-34-3(CAS DataBase Reference)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 3
F ?????? 10
HS ?? 29062990
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
2 0

(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)??? C??? ??, ??, ??

??? ??

yellow crystalline powder

??

These enantiomerically pure (+)- and (?)-2,2,2-trifluoro-1-(9-anthryl)ethanols have been used for the NMR spectral determination of optical purity (and in some cases, absolute configuration) of a wide variety of sulfoxides, lactones, amines, sulfinate esters, oxaziridines and allenes.

(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)??? ?? ?? ? ???

???

?? ??

(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)??? ?? ??

???( 73)?? ??
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(R)-(-)-2,2,2-TRIFLUORO-1-(9-ANTHRYL)??? ?? ??:

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