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ChemicalBook >> CAS DataBase List >>Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride

CAS No.
228120-95-4
Chemical Name:
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
Synonyms
(S)-RuCl[(p-cymene)(T-BINAP)]Cl;[RuCl(p-cymene)((S)-tolbinap)]Cl;(S)-RuCl[(p-cymene)(T-BINAP)]Cl;-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl;Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((S)-tolbinap)]Cl，95%
CBNumber:
CB81181041
Molecular Formula:
C58H52Cl2P2Ru
Molecular Weight:
982.97
MDL Number:
MFCD09753014
MOL File:
228120-95-4.mol
Last updated:2025-01-27 09:38:02

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Properties

Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form solid
color yellow to dark brown
Sensitive air sensitive
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3
HS Code  2843.90.0000

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 692964 (S)-RuCl[(p-cymene)(T-BINAP)]Cl 228120-95-4 500mg $51.2 2024-03-01 Buy
Sigma-Aldrich 692964 (S)-RuCl[(p-cymene)(T-BINAP)]Cl 228120-95-4 100mg $32.9 2023-06-20 Buy
TCI Chemical R0149 [RuCl(p-cymene)((S)-tolbinap)]Cl 228120-95-4 200mg $50 2024-03-01 Buy
TCI Chemical R0149 [RuCl(p-cymene)((S)-tolbinap)]Cl 228120-95-4 1g $162 2024-03-01 Buy
Strem Chemicals 44-0089 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl 228120-95-4 250mg $53 2024-03-01 Buy
Product number Packaging Price Buy
692964 500mg $51.2 Buy
692964 100mg $32.9 Buy
R0149 200mg $50 Buy
R0149 1g $162 Buy
44-0089 250mg $53 Buy

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Chemical Properties,Uses,Production

Reactions

1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
2. Ligand for palladium-catalyzed α-arylation of ketones.
3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
5. Enantioselective conjugate reduction of lactones and lactams.
6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
7. Catalytic Aldol reaction to ketones.
8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
11. Rhodium-catalyzed cross cyclotrimerization.
Reactions of 228120-95-4_1
Reactions of 228120-95-4_2

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 52)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29856 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
Richest Group Ltd 		18017061086 oled@richest-group.com CHINA 5600 58
changzhou huayang technology co., ltd 		+8615250961469 2571773637@qq.com China 9647 58
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
Zibo Hangyu Biotechnology Development Co., Ltd 		+86-0533-2185556 +8615965530500 nickzhang@hangyubiotech.com China 10968 58
Aladdin Scientific 		tp@aladdinsci.com United States 57505 58
Anhuyan (Hainan) Biotechnology Co., LTD 		+8618163349544 mollylucking@foxmail.com China 2764 58
Wuhan Fortuna Chemical Co.,Ltd 		+8618007136271 hk@fortunachem.com China 5992 58
DAYANG CHEM (HANGZHOU) CO.,LTD 		+86-88938639 +86-17705817739 info@dycnchem.com China 53900 58

View Lastest Price from Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride pictures 2019-08-09 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride
228120-95-4
 US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co
Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (S)-RuCl[(p-cymene)(T-BINAP)]Cl [RuCl(p-cymene)((S)-tolbinap)]Cl Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-tolbinap)]Cl -binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-tolbinap)]Cl Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride, [RuCl(p-cymene)((S)-tolbinap)]Cl，95% (S)-RuCl[(p-cymene)(T-BINAP)]Cl 228120-95-4 C58H54ClP2RuCl8722 Ru