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ChemicalBook >> CAS DataBase List >>Allyltributyltin

Allyltributyltin

CAS No.
24850-33-7
Chemical Name:
Allyltributyltin
Synonyms
ALLYLTRIBUTYLSTANNANE;ALLYLTRI-N-BUTYLTIN;Tributylallylstannane;allyltri-n-butylstannane;2-Propenyltributylstannane;TRIBUTYL-2-PROPENYLSTANNANE;SKL1093;ALLYLTRIBUTYLTIN;Allytri-N-Butyltin;allyitri－n－butyltin
CBNumber:
CB3257937
Molecular Formula:
C15H32Sn
Molecular Weight:
331.12
MDL Number:
MFCD00010346
MOL File:
24850-33-7.mol
Last updated:2025-02-23 21:28:46

Allyltributyltin Properties

Melting point 134-135 °C
Boiling point 88-92 °C0.2 mm Hg(lit.)
Density 1.068 g/mL at 25 °C(lit.)
refractive index n20/D 1.486(lit.)
Flash point >230 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Liquid
color Clear colorless
Specific Gravity 1.068
Water Solubility Immiscible with water.
Sensitive Air Sensitive
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems
BRN 3588340
Exposure limits ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
Stability Air Sensitive
InChIKey YLGRTLMDMVAFNI-UHFFFAOYSA-N
CAS DataBase Reference 24850-33-7(CAS DataBase Reference)
FDA UNII AOR8OD4103
NIST Chemistry Reference Allyltributyltin(24850-33-7)
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H312-H315-H319-H360FD-H372-H410
Precautionary statements  P201-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338
Hazard Codes  T,N
Risk Statements  21-25-36/38-48/23/25-50/53-23/24/25
Safety Statements  35-36/37/39-45-60-61-28-27-26
RIDADR  UN 2788 6.1/PG 2
WGK Germany  3
F  13
TSCA  No
HazardClass  6.1
PackingGroup  II
HS Code  29319019
NFPA 704
0
3 0

Allyltributyltin price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 271411 Allyltributylstannane 97% 24850-33-7 5g $62.7 2024-03-01 Buy
Sigma-Aldrich 271411 Allyltributylstannane 97% 24850-33-7 25g $136 2024-03-01 Buy
Alfa Aesar L14087 Allyltri-n-butyltin, 97% 24850-33-7 5g $39.6 2023-06-20 Buy
Alfa Aesar L14087 Allyltri-n-butyltin, 97% 24850-33-7 25g $136 2023-06-20 Buy
Sigma-Aldrich 271411 Allyltributylstannane 97% 24850-33-7 100g $290 2024-03-01 Buy
Product number Packaging Price Buy
271411 5g $62.7 Buy
271411 25g $136 Buy
L14087 5g $39.6 Buy
L14087 25g $136 Buy
271411 100g $290 Buy

Allyltributyltin Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595). Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones and allyl acetates.
Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.

Uses

Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Purification Methods

A possible impurity is tributylchlorostannane — test for Cl as Cl ion after hydrolysing. Dissolve it in *C6H6 (or toluene), shake this with dilute aqueous NaOH, dry (CaCl2), filter, evaporate and distil the residue in a vacuum [Jones et al. J Chem Soc 1446 1947, Bristow Aldrichimica Acta 17 75 1984, Yamamoto Aldrichimica Acta 20 45 1987]. [Beilstein 4 IV 4317.]

80883-02-9
106-95-6
24850-33-7
Synthesis of Allyltributyltin from Tributyltin hydroxide and Allyl bromide
Global( 229)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Kaitian Chemical Co., LTD
+undefined13337835376 kt_chem@126.com China 40 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21631 55
Shanghai Arbor Chemical Co., Ltd. 		021-60451682 act@arborchemical.com CHINA 904 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58
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Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Xi'an MC Biotech, Co., Ltd. 		029-89275612 +8618991951683 mcbio_sales@163.com China 2251 58

View Lastest Price from Allyltributyltin manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Allyltributyltin pictures 2025-03-03 Allyltributyltin
24850-33-7
 US $0.00 / kg 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
Allyltributyltin pictures 2023-04-11 Allyltributyltin
24850-33-7
 US $0.00-0.00 / kg 1kg 98% 1 ton Nanjing Kaitian Chemical Co., LTD
Allyltributyltin pictures 2020-01-09 Allyltributyltin
24850-33-7
 US $6.68 / KG 1KG 97%-99% 1kg-1000kg Career Henan Chemical Co
  • Allyltributyltin pictures
  • Allyltributyltin
    24850-33-7
  • US $0.00-0.00 / kg
  • 98%
  • Nanjing Kaitian Chemical Co., LTD
Stannane, tributyl-2-propenyl- ALLYLTRIBUTYLTIN ALLYLTRIBUTYLTIN(IV) Allytri-N-Butyltin Allyltri-n-butyltin,97% (2-Propenyl)tributylstannane Allyltributyltin,97% Allyltributyltin(Ⅳ) allyitri－n－butyltin tri-n-butyl-2-propenylstannane Allyltributylstannane 97% The threebutyltinpropenyl Allyltributyltin, 97% 1GR (Prop-2-en-1-yl)tributyl stannane, 3-(Tributylstannyl)prop-1-ene 3-(Tributylstannyl)prop-1-ene Stannane, tributyl-2-propen-1-yl- Allyltributyltin ISO 9001：2015 REACH SKL1093 tributyl(prop-2-enyl)stannane ALLYLTRIBUTYLSTANNANE ALLYLTRI-N-BUTYLTIN TRIBUTYL-2-PROPENYLSTANNANE 2-Propenyltributylstannane Tributylallylstannane allyltri-n-butylstannane ributyl(prop-2-enyl)stannane Allyl Tri n-butyl tin /stannane 24850-33-7 CH2CHCH2SnCH2CH2CH2CH33 Classes of Metal Compounds Alkyl Metals Sn (Tin) Compounds Typical Metal Compounds Grignard Reagents & Alkyl Metals Organotin Organotins Organometallic Reagents Organotins Stannanes Chemical Synthesis Organometallic Reagents Alkyl Metals Sn (Tin) Compounds Classes of Metal Compounds Grignard Reagents & Alkyl Metals Synthetic Organic Chemistry Typical Metal Compounds Organometallic Reagents Organotin