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ChemicalBook--->CAS DataBase List--->909393-65-3

909393-65-3

909393-65-3 Structure

909393-65-3 Structure
IdentificationBack Directory
[Name]

Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4
[CAS]

909393-65-3
[Synonyms]

Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
Tetrakis[(R)-(-)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(R-PTAD)4
Tetrakis[mu-[(alphaR)-1,3-dihydro-1,3-dioxo-alpha-tricyclo[3.3.1.1(3,7)]dec-1-yl-2H-isoindole-2-acetato]]dirhodium
[Molecular Formula]

C80H80N4O16Rh2
[MDL Number]

MFCD09839139
[MOL File]

909393-65-3.mol
[Molecular Weight]

1559.34
Chemical PropertiesBack Directory
[Melting point ]

>300°C
[alpha ]

-40.6 (c 0.067, CHCl3)
[form ]

Powder
[color ]

green
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H335-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Questions and Answers (Q&A)Back Directory
[Reactions]

  1. Enantioselective reactions of carbenoids and olefins.
  2. Enantioselective C–H insertion reactions of carbenoids.
  3. Enantioselective oxygen transfer from diazosulfonylamidines. 
Reactions of 909393-65-3
Hazard InformationBack Directory
[Uses]

This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control.
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