77299-63-9

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77299-63-9 Structure

Identification	Back Directory
[Name] Lithium diisobutyl-tert-butoxyaluminum hydride
[CAS] 77299-63-9
[Synonyms] LDBBA -tert-butoxyaL ithium diisobutyL Lithium diisobutyl-tert-butoxyaluminum hydride Lithium diisobutyl-tert-butoxyaluminum hydride solution Lithium diisobutyl-tert-butoxyaluminum hydride solution 0.25M in THF/hexanes Lithium diisobutyl-tert-butoxyaluminum hydride 0.25 M in THF/hexanes solution LithiuM diisobutyl-tert-butoxyaluMinuM hydride, 0.25 M solution in THF/hexanes
[Molecular Formula] C12H28AlLiO
[MDL Number] MFCD16621454
[MOL File] 77299-63-9.mol
[Molecular Weight] 222.273

Chemical Properties	Back Directory
[density ] 0.795 g/mL at 25 °C
[storage temp. ] 2-8°C
[form ] liquid
[InChI] InChI=1S/C4H9O.2C4H8.Al.Li.H/c1-4(2,3)5;21-4(2)3;;;/h1-3H3;21,4H,2-3H3;;;/q3*-1;+2;+1;
[InChIKey] AHOWROKZHSVLIH-UHFFFAOYSA-N
[SMILES] [O-](C(C)(C)C)[Al+3]([H-])([CH-]C(C)C)[CH-]C(C)C.[Li+]

Safety Data	Back Directory
[Symbol(GHS) ] GHS02,GHS07,GHS08,GHS09
[Signal word ] Danger
[Hazard statements ] H261-H304-H315-H319-H335-H336-H351-H361f-H373-H411
[Precautionary statements ] P231+P232-P260-P280-P301+P310-P370+P378-P402+P404
[Hazard Codes ] F,Xn,N
[Risk Statements ] 15-19-36/37/38-40-48/20-51/53-62-65-67
[Safety Statements ] 26-36/37-43-61-62
[RIDADR ] UN 3399BC 4.3(3) / PGII
[WGK Germany ] 3

Hazard Information	Back Directory
[Uses] Lithiumdiisobutyl-tert-butoxyaluminum hydride solution can be used as a reducing agent for the reduction of: Aromatic and aliphatic nitriles to aldehydes. Aromatic and aliphatic esters to aldehydes. Tertiary amides to aldehydes.
[reaction suitability] reagent type: reductant

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