| Identification | Back Directory | [Name]
CYCLOHEXYLZINC BROMIDE | [CAS]
7565-57-3 | [Synonyms]
CYCLOHEXYLZINC BROMIDE
bromozinc(1+),cyclohexane
cyclohexylzinc(II) broMide
cyclohexylzinc bromide solution
Cyclohexylzinc bromide, 0.5 M in THF
Cyclohexylzinc bromide, 0.50 M in THF
Cyclohexylzinc bromide solution 0.5 in THF
Cyclohexylzinc broMide solution 0.5 M in THF
Cyclohexylzinc broMide, 0.5 M solution in THF, SpcSeal
CYCLOHEXYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
Cyclohexylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
Cyclohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | [Molecular Formula]
C6H11BrZn | [MDL Number]
MFCD00671993 | [MOL File]
7565-57-3.mol | [Molecular Weight]
228.45 |
| Chemical Properties | Back Directory | [Melting point ]
114.0-116.0 °C | [density ]
0.963 g/mL at 25 °C
| [Fp ]
3 °F
| [storage temp. ]
2-8°C | [Water Solubility ]
Reacts with water. | [Sensitive ]
Air Sensitive | [Exposure limits]
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Hazard Information | Back Directory | [Uses]
Cyclohexylzinc bromide is an organozinc reagent, generally used in Negishi coupling. Examples include the cross-coupling of alkylzinc halides with aryl/heteroaryl halides using Pd-PEPPSI-IPent and nickel-catalyzed synthesis of 4-substituted coumarins.
It can react with the SO2 surrogate, 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) adduct (DABSO) to afford zinc sulfinate salts which can be alkylated to synthesize various useful sulfones. | [Uses]
It is used as primary and secondary intermediate. |
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