| Identification | Back Directory | [Name]
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE | [CAS]
71042-54-1 | [Synonyms]
(S,S)-NORPHOS
(2S,3S)-(+)-Norphos
(1R,4S,5S,6S)-5,6-Dibenzhydrylbicyclo[2.2.1]hept-2-ene
(1S,4R)-5α,6β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene,95%
(1R,2S,3S,4S)-Bicyclo[2.2.1]hept-5-ene-2,3-diylbis[diphenylphosphine]
[1R,2S,3S,4S,(+)]-2α,3β-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
[1R,2S,3S,4S,(+)]-2α,3β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-5-ene
[[1R,4S,(+)]-Bicyclo[2.2.1]hept-5-ene-2α,3β-diyl]bis(diphenylphosphine)
[[1R,4S,(+)]-Bicyclo[2.2.1]hepta-5-ene-2α,3β-diyl]bis(diphenylphosphine)
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95%
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene, (S,S)-NORPHOS
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene (S,S)-NORPHOS
Phosphine,1,1'-(1R,2S,3S,4S)-bicyclo[2.2.1]hept-5-ene-2,3-diylbis[1,1-diphenyl-
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene,min.95%(S,S)-NORPHOS
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene, Min. 97% (S,S)-NORPHOS
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE (S,S)-NORPHOS, (C 1,CHCL3) | [Molecular Formula]
C31H28P2 | [MDL Number]
MFCD00085364 | [MOL File]
71042-54-1.mol | [Molecular Weight]
462.5 |
| Chemical Properties | Back Directory | [Appearance]
White crystalline powder | [Melting point ]
120 °C | [alpha ]
+47° (c 1, CHCl3) | [form ]
crystal | [color ]
white | [Sensitive ]
air sensitive |
| Questions And Answer | Back Directory | [Reaction]
- Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
- Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
- Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
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