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ChemicalBook--->CAS DataBase List--->693-04-9

693-04-9

693-04-9 Structure

693-04-9 Structure
IdentificationMore
[Name]

Butylmagnesium chloride
[CAS]

693-04-9
[Synonyms]

BUTYLMAGNESIUM CHLORIDE
N-BUTYLMAGNESIUM CHLORIDE
Butylmagnesium
BUTYLMAGNESIUM CHLORIDE,1.45M SOLUTION IN BUTYL DIGLYME
BUTYLMAGNESIUM CHLORIDE SOLUTION, ~2 M I N THF
BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN
BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N DIETHYL ETHER
BUTYLMAGNESIUM CHLORIDE 2.0M SOLUTION &
n-Butylmagnesium Chloride 2.0 M In Diethyl Ether
n-Butylmagnesium Chloride 2.0 M In Tetrahydrofuran
n-Butylmagnesiumchloride,1.5-2.5MinTHF
n-Butylmagnesium chloride, 20 wt% solution in THF/Toluene
n-Butylmagnesiumchloride,1.5-3.0MinTHF
Magnesium, butylchloro-
butylmagnesium chloride solution
n-butylmagnesium chloride, 1.5-2.5m in thf, packaged under argon in resealable chemseal
n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSealTM bottles
Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSeal bottles
Butyl(chloro)magnesium
[EINECS(EC#)]

211-739-5
[Molecular Formula]

C4H9ClMg
[MDL Number]

MFCD00000475
[Molecular Weight]

116.87
[MOL File]

693-04-9.mol
Chemical PropertiesBack Directory
[Appearance]

green-brown to brown solution
[Melting point ]

-17°C
[Boiling point ]

66°C
[density ]

0.962 g/mL at 25 °C
[Fp ]

115 °F
[storage temp. ]

2-8°C
[form ]

Solution
[color ]

Green-brown to brown
[Water Solubility ]

reacts
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

3587228
[InChIKey]

UUNGXYVLXYGZKH-UHFFFAOYSA-M
[CAS DataBase Reference]

693-04-9(CAS DataBase Reference)
[EPA Substance Registry System]

693-04-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C,F,F+
[Risk Statements ]

R12:Extremely Flammable.
R14/15:Reacts violently with water, liberating extremely flammable gases .
R19:May form explosive peroxides.
R22:Harmful if swallowed.
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
R15:Contact with water liberates extremely flammable gases.
R14:Reacts violently with water.
R10:Flammable.
[Safety Statements ]

S7:Keep container tightly closed .
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S46:If swallowed, seek medical advice immediately and show this container or label .
[RIDADR ]

UN 3399 4.3/PG 2
[WGK Germany ]

1
[F ]

10
[TSCA ]

Yes
[HazardClass ]

4.3
[PackingGroup ]

II
[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

3-Quinolinecarboxaldehyde-->1-(4-Bromophenyl)hexane-->Ethyl silicate-->UNDECANE,5-METHYL--->N,N-Diethyldecanamide-->1-NITROBUTANE-->BUTYLMAGNESIUM DIISOPROPYLAMIDE 1.0 M-->ETHYL 8-OXODODECANOATE-->2-broMo-6-(triMethylsilyl)pyridine
Hazard InformationBack Directory
[Chemical Properties]

green-brown to brown solution
[Uses]

n-Butylmagnesium chloride is used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.
[reaction suitability]

reaction type: Grignard Reaction
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

n-Butylmagnesium chloride, 20 wt% solution in THF/Toluene, AcroSeal?(693-04-9)
[Alfa Aesar]

n-Butylmagnesium chloride, 1.5-2.5M in THF, packaged under Argon in resealable ChemSeal™ bottles(693-04-9)
[Sigma Aldrich]

693-04-9(sigmaaldrich)
[TCI AMERICA]

Butylmagnesium Chloride  (23% in Tetrahydrofuran, ca. 2mol/L)(693-04-9)
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